Physico-chemical forms of copper in water and sediments of Lake Pontchartrain basin, USA.

Abstract:

:In this study, one of the largest estuaries in the Gulf Coast of USA was investigated for Cu forms and fractionations. Both the water and sediment samples in subsegments of the Lake Pontchartrain basin were collected and Cu forms in dissolved phase and sediment phase were analyzed. The BCR sequential extraction procedure was used to extract Cu in exchangeable, reducible, oxidizable and residual fractions in sediments. The results showed that the residual fraction of Cu was a major contributor in Tangipahoa River and I-10 Bridge sediments, while the residual and oxidizable fractions in the case of oil refinery sediments. Cu partitioning in Lake Pontchartrain basin water showed the decreasing trend of inert > labile > organic in both spring and summer. The release of Cu from the sediments into the water column was greater in summer as compared to spring and vice versa. Lower temperature helps in the adsorption of Cu on the surface of sediments in early spring due to low disturbance and temperature.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Zhang Z,Wang JJ,Ali A,DeLaune RD

doi

10.1016/j.chemosphere.2017.12.115

subject

Has Abstract

pub_date

2018-03-01 00:00:00

pages

448-454

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(17)32085-4

journal_volume

195

pub_type

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