Abstract:
:A poly(l-serine)-modified glassy carbon electrode (PLS/GCE) was fabricated by electropolymerization and used to study the detection of naproxen (NPX), a representative non-steroidal anti-inflammatory drug, in phosphate buffer supporting electrolyte at pH 5.0. Results indicated that the PLS/GCE was capable of determination of NPX at a working potential of 0.92 (vs. Ag/AgCl) in voltammetry mode. Experimental factors such as scan rate, accumulation time, solution pH, initial NPX concentration, and interferences were optimized for NPX determination efficiency. The morphology and elemental distribution of the electrode surface were characterized by ESEM, TEM, PSD, XRD, FTIR, TGA, XPS, and zeta potential. NPX oxidation current increased with increasing analyte concentration and scan rate but decreased with increasing pH. Linear sweep voltammetry calibration curve was established in the NPX concentration range of 4.3-65 μM, with detection limit and average recovery of 0.69 μM (n = 3) and 104 ± 2.5%, respectively. PLS/GCE is simple, accurate, reproducible, and easy for operation, therefore would be cost-effective for the determination of NPX.
journal_name
Chemospherejournal_title
Chemosphereauthors
Hung CM,Huang CP,Chen SK,Chen CW,Dong CDdoi
10.1016/j.chemosphere.2020.126686subject
Has Abstractpub_date
2020-09-01 00:00:00pages
126686eissn
0045-6535issn
1879-1298pii
S0045-6535(20)30879-1journal_volume
254pub_type
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