Fate of selected neonicotinoid insecticides in soil-water systems: Current state of the art and knowledge gaps.

Abstract:

:The occurrence of emerging contaminants, such as: personal care products, medicines, pharmaceuticals, pesticides, and their transformation products in the environment is of concern for human health and aquatic ecosystems due to their high persistence, toxicity and potential to bioaccumulation. Among pesticides, the main attention and thus our focus is on neonicotinoids: acetamiprid, clothianidin, imidacloprid, thiacloprid and thiamethoxam, which are widely used classes of insecticides in agriculture. Determining the associated risk to humans and ecosystems from neonicotinoid insecticides requires detailed understanding of their fate and transport in the environment which is complex and includes diverse pathways and processes depending on environmental compartments in which they occur. This paper critically reviews the current state of the art about processes, parameters and phenomena influencing the fate of neonicotinoid insecticides in soil-water systems (i.e. soil and groundwater), and reveals existing knowledge gaps. Sorption, biodegradation, chemical transformations of neonicotinoid insecticides in the soil and leaching to the groundwater, as well as groundwater/surface water interactions are highlighted, as they determine their further migration from sources, through soils to groundwater systems and then to other environmental compartments posing ecological and human risks. A number of key knowledge gaps in fate of neonicotinoid insecticides in soil-water systems are identified, that concern mostly processes and pathways occurring in the groundwater, and require further research to assess the associated risk to humans and ecosystems.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Pietrzak D,Kania J,Kmiecik E,Malina G,Wątor K

doi

10.1016/j.chemosphere.2020.126981

subject

Has Abstract

pub_date

2020-09-01 00:00:00

pages

126981

eissn

0045-6535

issn

1879-1298

pii

S0045-6535(20)31174-7

journal_volume

255

pub_type

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