Abstract:
:The waste rock, tailings and soil around an abandoned mine site in Gorno (northwest Italy) contain elevated concentrations of potentially toxic elements (PTE) exceeding the permissible limits for residential uses. Specifically, the maximum concentrations of As, Cd, Pb, and Zn were 107 mg/kg, 340 mg/kg, 1064 mg/kg, and 148 433 mg/kg, respectively. A site-specific human health risk assessment (HHRA) was conducted for residential and recreational exposure scenarios, using an approach based on Risk Based Corrective Action (RBCA) method, refined by incorporating oral bioaccessibility data. Oral bioaccessibility analyses were performed by simulating the human digestion process in vitro (Unified BARGE Method). Detailed analysis of oral bioaccessible fraction (BAF i.e. ratio of bioaccessible concentrations to total concentrations on <250 μm fraction) indicated BAF of As (5-33%), Cd (72-98%), Co (24-42%), Cr (3-11%), Cu (25-90%), Ni (17-60%), Pb (16-88%) and Zn (73-94%). The solid phase distribution and mineralogical analyses showed that the variation of BAF is attributed to presence of alkaline calcareous rocks and association of PTE with a variety of minerals. The HHRA for ingestion pathway, suggested that bioaccessibility-corrected cancer risk reached up to 2.7 × 10-5 and 0.55 × 10-5 for residential and recreational senarios respectively (acceptable level is 1 × 10-5). The hazard index (HI) recalculated after incorporation of oral bioaccessible concentrations for a residential scenario ranged from 0.02 to 17.9. This was above the acceptable level (>1) for 50% of the samples, indicating potential human health risks. This study provides information for site-specific risk assessments and planning future research.
journal_name
Chemospherejournal_title
Chemosphereauthors
Mehta N,Cipullo S,Cocerva T,Coulon F,Dino GA,Ajmone-Marsan F,Padoan E,Cox SF,Cave MR,De Luca DAdoi
10.1016/j.chemosphere.2020.126927subject
Has Abstractpub_date
2020-09-01 00:00:00pages
126927eissn
0045-6535issn
1879-1298pii
S0045-6535(20)31120-6journal_volume
255pub_type
杂志文章相关文献
CHEMOSPHERE文献大全abstract::In this work, the findings of the first assessment of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in emissions releases to the atmosphere from coal-fired power plants are given. A total of five plants were selected for the study located at different provinces in Spain. In all the cases, the results r...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2004.04.053
更新日期:2004-10-01 00:00:00
abstract::In this study, (1) the change in the concentration of bisphenol A (BPA) leached from polycarbonate plastic (PCP) tube to water samples containing phosphate, sodium barbital, glycine, methionine or albumin at 37 degrees C as a function of time, and (2) the degradation rate of BPA leached from PCP tube to amino acid sol...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2003.11.065
更新日期:2004-05-01 00:00:00
abstract::For the interpretation of stable isotope ratio trends in saturated geochemical systems, the magnitude of aqueous phase diffusion-induced isotope fractionation needs to be known. This study reviews how five diffusion models (Fick, Maxwell-Stefan, Einstein, Langevin, Mode-Coupling Theory Analysis (MCTA) of diffusion) pr...
journal_title:Chemosphere
pub_type: 杂志文章,评审
doi:10.1016/j.chemosphere.2018.12.038
更新日期:2019-03-01 00:00:00
abstract::In this study, spatial distribution and chemical fractionation were conducted to appraise the overall classification of Al, B, Cd, Cr, and Pb as well as their ecological risks in Lake Qarun sediments. Also, the other chemical components (CaCO3, TOC, SO42-, SiO32-, PO43-, F, Ca, and Mg) that represented the chemical co...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.10.049
更新日期:2018-01-01 00:00:00
abstract::Pseudo-total (i.e. aqua regia extractable) and gastric-bioaccessible (i.e. glycine+HCl extractable) concentrations of Ca, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined in a total of 48 samples collected from six community urban gardens of different characteristics in the city of Madrid (Spain). Calcium carbonate a...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.04.079
更新日期:2015-09-01 00:00:00
abstract::Enantiomer separation of chiral toxaphene components in biological samples was studied by application of different chiral stationary phases based on modified cyclodextrins. Several pairs of enantiomers were resolved on permethylated beta-cyclodextrin (beta-PMCD), among them 2-endo,3-exo,5-endo,6-exo,8,8,9,10-octachlor...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(99)00478-6
更新日期:2000-08-01 00:00:00
abstract::The degradation and mineralization of ofloxacin (OFX) by ozonation and peroxone process (O3/H2O2) was investigated. The influence of operational conditions and inorganic anions on the mineralization of OFX were also studied. Results showed that OFX could be rapidly oxidized by both O3 alone and O3/H2O2 process. The mi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.128775
更新日期:2020-11-03 00:00:00
abstract::In order to understand the residue levels of organochlorine compounds (OCs) and their accumulation patterns in wildlife inhabiting Chubu region, Japan, the concentrations of polychlorinated biphenyls (PCBs), hexachlorocyclohexane isomers (HCHs), DDT compounds (DDTs) and hexachlorobenzene (HCB) were measured in 8 speci...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(98)00011-3
更新日期:1998-06-01 00:00:00
abstract::Previous studies with octachlorodibenzo-p-dioxin (OCDD) and octachlorodibenzofuran (OCDF) in juvenile or adult fish exposed via water revealed no toxicity, despite significant bioaccumulation. With 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), the fish early-life stage study has been shown to be the most sensiti...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/s0045-6535(97)00129-x
更新日期:1997-08-01 00:00:00
abstract::We developed a useful analytical method for the determination of polycyclic aromatic hydrocarbons (PAH) concentrations in the aerosol of China. We used an accelerated solvent extraction (ASE) method for the extraction of PAHs from the aerosol samples, in order to reduce the extraction time and the solvent volume used....
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.01.064
更新日期:2006-10-01 00:00:00
abstract::The levels and bioaccumulation of organochlorine pesticides (OCPs) and heavy metals were studied in muscle and liver of three fish species, with two trophic levels, from Lake Awassa, Ethiopia. DDTs were the predominant organic pollutant in all species with a maximum level of 73.28 ng g(-1) wet weight (ww). p,p'-DDE wa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2013.01.047
更新日期:2013-05-01 00:00:00
abstract::The interactions between metal and phytoplankton are affected by salinity in estuarine environments. While water chemistry is an important factor regulating the metal bioavailability in phytoplankton, the physiological adaptation of the algae cells may also change their intrinsic response to metals. In this work, we t...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.10.128
更新日期:2019-01-01 00:00:00
abstract::In aquatic environments the reactive oxygen species hydrogen peroxide (H2O2) is produced through photochemical reactions involving chromophoric dissolved organic matter (CDOM). Andean Patagonian freshwaters experience challenging underwater UV levels, which promote high levels of photochemical weathering. In this inve...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.10.179
更新日期:2019-02-01 00:00:00
abstract::A series of alkyl bicarbamates supramolecular organogelators were synthesized with different structures and lengths of alkyl chains. The driving forces for the self-assembly of small molecules, including the intermolecular H bonding, π-π stacking and van der Waals interactions, played an important role in the formatio...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.09.149
更新日期:2017-01-01 00:00:00
abstract::MSWI(Municipal solid waste incineration) fly ash as hazardous wastes usually is treated properly with OPC(ordinary Portland cement) based binders prior to being disposed in security landfill, but some toxic elements present poor stability in its highly alkaline environment. This study developed a novel solidification/...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126269
更新日期:2020-07-01 00:00:00
abstract::The study provides cumulative data on the status of the two water bodies. The study designed revealed physicochemical properties (temperature, dissolved oxygen, pH, total dissolved solids and conductivity) to be in the desirable range, however, amongst the heavy metals excepting for Cd all were found to be higher than...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2020.126311
更新日期:2020-07-01 00:00:00
abstract::Almost 8 years after the Japanese Fukushima Daiichi Nuclear Power Plant (FDNPP) accident, data for 236U and 236U/238U have mainly remained limited to only a few heavily contaminated samples. In the present study, activities of 236U, 134Cs, and 137Cs, along with 234U, 235U, 238U, in 15 river bank soil and 10 river sedi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.03.061
更新日期:2019-06-01 00:00:00
abstract::In order to evaluate the combined effect of adsorption and biodegradation of H(2)S on activated carbon surface in biotrickling filtration, four laboratory-scale biofiltration columns were operated simultaneously for 120h to investigate the mechanisms involved in treating synthetic H(2)S streams using biological activa...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.07.020
更新日期:2007-01-01 00:00:00
abstract::Quantitative structure-property relationship (QSPR) models which predict hydroxyl radical rate constants (kOH) for a wide range of emerging micropollutants are a cost effective approach to assess the susceptibility of these contaminants to advanced oxidation processes (AOPs). A QSPR model for the prediction of kOH of ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2015.05.034
更新日期:2015-11-01 00:00:00
abstract::The effects of multiple heavy metal stress on the activity of antioxidative enzymes and lipid peroxidation were studied in leaves and roots of two mangrove plants, Kandelia candel and Bruguiera gymnorrhiza, grown under control (10 per thousand NaCl nutrient solution) or five levels of multiple heavy metal stress (10 p...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.10.007
更新日期:2007-02-01 00:00:00
abstract::Although use of organochlorine pesticides (OCPs) has been banned or severely limited on a global basis, concerning concentrations continue to be reported in many tropical and subtropical regions of the world. These habitats often support high levels of unique biodiversity and vulnerable communities that depend on the ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2021.129712
更新日期:2021-01-25 00:00:00
abstract::The activities of heterogeneous Fenton and Photo-Fenton processes using pyrite (FeS2) prepared via a solvethermal method were evaluated by oxidation of p-nitrophenol (PNP). PNP could be completely ultrarapidly oxidized by Pyrite-Photo-Fenton (Pyrite-PF) system within 4 min, versus 10 min in Pyrite-Fenton (Pyrite-F) sy...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.04.103
更新日期:2019-08-01 00:00:00
abstract::Parasitoids acting as biocontrol agents provide farmers with valuable ecosystem services, but are sensitive to insecticides applied against pests. Besides lethal effects of insecticides, sublethal effects observed among survivors may further influence parasitoids' performance. However, information on sublethal effects...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.09.132
更新日期:2019-01-01 00:00:00
abstract::Transfer of indicator polychlorobiphenyls (PCBs) from soil into hen eggs may occur in hens reared outdoor, which ingest significant amounts of soil. This transfer depends on the bioavailability of the ingested compounds. The impact of soil on the bioavailability of indicator PCBs was assessed by means by a relative bi...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2012.02.041
更新日期:2012-07-01 00:00:00
abstract::Evidence has shown that exposure to fine particulate matter (PM) contributed to poor semen quality in males. However, the reproductive toxicity and relevant molecular mechanisms of Particular Matter 2.5 (PM2.5) from different seasons are not well understood. In the present work, we intend to investigate the toxic effe...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2017.09.082
更新日期:2017-12-01 00:00:00
abstract::This study investigated the degradation efficiency of BTA using combination of ultrasound (US), peroxymonosulfate (PMS), and ozone. The effects of different operational parameters were investigated to optimize the process performance. The results showed that the highest removal efficiency was reached at neutral pH, oz...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.125326
更新日期:2020-04-01 00:00:00
abstract::The concentrations and distributions of polybrominated diphenyl ethers (PBDEs) and novel brominated flame retardants (NBFRs) in tree bark and hair samples from the same area in Yunnan Province, China, were determined. The total PBDE and NBFR concentrations in the tree bark samples were 3.8 ng/g lipid weight to 91 ng/g...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2016.03.132
更新日期:2016-07-01 00:00:00
abstract::Ability of hexavalent chromium to accumulate and induce oxidative stress has been studied in the gills of Ctenopharyngodon idellus, with the resulting damage in the form of altered endogenous antioxidant enzyme activity and, histopathology in the tissue. The fish were exposed to 5.3 (C1) and 10.63 mg/L (C2) of hexaval...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2019.05.027
更新日期:2019-09-01 00:00:00
abstract::Two-photon resonance enhanced multiphoton ionization (REMPI) has been shown to be a unique ionization method for mass spectrometry, exhibiting both high sensitivity and chemical selectivity. Because REMPI is a gas-phase method, its applications have been limited either to direct analysis of vapor phase samples, or in ...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2006.05.117
更新日期:2007-04-01 00:00:00
abstract::This study focused on an estuarine wildlife species exhibiting high site fidelity and ubiquitous distribution in coastal environments along the Atlantic and Gulf coasts of the United States to monitor per- and polyfluoroalkyl substances (PFAS). A total of 75 diamondback terrapin (Malaclemys terrapin) plasma samples we...
journal_title:Chemosphere
pub_type: 杂志文章
doi:10.1016/j.chemosphere.2018.10.023
更新日期:2019-01-01 00:00:00