Oestrogenicity assessment of s-triazines by-products during ozonation.

Abstract:

:The triazines are a group of herbicides with a wide range of uses. Atrazine is, in fact, one of the most used agricultural pesticides in the world. The terbuthylazine is applied as a substitute of atrazine in some countries of Europe since 2004, when the European Union announced a ban of atrazine because of ubiquitous water contamination. In this study, both atrazine and terbuthylazine were degraded by the ozone process to estimate the efficiency on pesticide removal in water, the intermediates formed and their potential oestrogenic activity using the yeast oestrogen screen (YES) test. Both pesticides were rapidly eliminated from the medium during ozonation (applied ozone dose 0.083 and 0.02 mmol O3 L(-1), respectively). The results show that both compounds generated similar by-products from ozone degradation. Moreover, significant oestrogenic activity was detected for both atrazine and terbuthylazine intermediates, during the first minutes of ozonation. The YES assay used in this study proved to be a sensitive tool in assessing trace amounts of oestrogenic chemicals, which can represent critical issues influencing the experimental results in environmental applications.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Pereira SV,Reis T,Souza BS,Dantas RF,Azevedo DA,Dezotti M,Sans C,Esplugas S

doi

10.1080/09593330.2014.995235

subject

Has Abstract

pub_date

2015-05-01 00:00:00

pages

1538-46

issue

9-12

eissn

0959-3330

issn

1479-487X

journal_volume

36

pub_type

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