Electrochemical treatment of cork boiling wastewater with a boron-doped diamond anode.

Abstract:

:Anodic oxidation at a boron-doped diamond anode of cork boiling wastewater was successfully used for mineralization and biodegradability enhancement required for effluent discharge or subsequent biological treatment, respectively. The influence of the applied current density (30-70 mA/cm2) and the background electrolyte concentration (0-1.5 g/L Na2SO4) on the performance of the electrochemical oxidation was investigated. The supporting electrolyte was required to achieve conductivities that enabled anodic oxidation at the highest current intensities applied. The results indicated that pollutant removal increased with the applied current density, and after 8 h, reductions greater than 90% were achieved for COD, dissolved organic carbon, total phenols and colour. The biodegradability enhancement was from 0.13 to 0.59 and from 0.23 to 0.72 for the BOD/COD ratios with BOD of 5 and 20 days' incubation period, respectively. The tests without added electrolyte were performed at lower applied electrical charges (15 mA/cm2 or 30 V) with good organic load removal (up to 80%). For an applied current density of 30 mA/cm2, there was a minimum of electric conductivity of 1.9 mS/cm (corresponding to 0.75 g/L of Na2SO4), which minimized the specific energy consumption.

journal_name

Environ Technol

journal_title

Environmental technology

authors

Fernandes A,Santos D,Pacheco MJ,Ciríaco L,Simões R,Gomes AC,Lopes A

doi

10.1080/09593330.2014.934743

subject

Has Abstract

pub_date

2015-01-01 00:00:00

pages

26-35

issue

1-4

eissn

0959-3330

issn

1479-487X

journal_volume

36

pub_type

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