Structure and conformation of photosynthetic pigments and related compounds 7. On the conformation of the methyl ester of (20-methyl-phytochlorinato)nickel(II)--a bacteriochlorophyll c model compound.

Abstract:

:The crystal and molecular structure of the title compound 4 have been determined by single crystal X-ray crystallography. The structure shows the typical S4-ruffled conformation observed for Ni(II) tetrapyrroles. Compared to the structure of the methyl ester of (13(2)-demethoxycarbonyl-pheophorbidato a)nickel(II), 4 shows a smaller Ca-Cm-Ca angle and a higher degree of conformational distortion at the methyl-substituted C20 position. This local distortion of the macrocycle might account for the bathochromic shifted absorption spectra of the bacteriochlorophylls c compared to the d-series. Crystal data: C35H38N4NiO3; tetragonal, P4(3)2(1)2, a = 15.335(7) A, c = 25.11(2) A, V = 5904, Z = 8, lambda(Mo K alpha) = 0.71069 A, mu = 0.701 mm-1, F(000) = 2624, 130 K, R = 0.058 for 5700 reflections with F > 4.0 sigma(F).

journal_name

Photochem Photobiol

authors

Senge MO,Smith KM

doi

10.1111/j.1751-1097.1994.tb05080.x

subject

Has Abstract

pub_date

1994-08-01 00:00:00

pages

139-42

issue

2

eissn

0031-8655

issn

1751-1097

journal_volume

60

pub_type

杂志文章
  • On the possibility of evanescent wave excitation distal from a solid-liquid interface using light quenching.

    abstract::Evanescent wave illumination with total internal reflection is often used to provide excitation near a quartz-water interface. We now show that evanescent illumination at one wavelength and incident angle, coupled with light quenching at a second wavelength and incident angle, can be used for selective excitation of f...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1996.tb03117.x

    authors: Lakowicz JR,Gryczynski Z,Gryczynski I

    更新日期:1996-10-01 00:00:00

  • Photooxidation of tryptophan leading to 2-aminoacetophenone--a possible reason for the untypical aging off-flavor in wine.

    abstract::2-Aminoacetophenone (AAP) was recognized as the key compound for the so-called untypical aging off-flavor (UTA) in Vitis vinifera wines. In this study, it was shown that AAP can be formed by photooxidation of free and protein-bound tryptophan (TRP) in combination with a subsequent storage in model wine. Solutions of T...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12321

    authors: Horlacher N,Schwack W

    更新日期:2014-11-01 00:00:00

  • Mechanism of UV-induced IkappaBalpha-independent activation of NF-kappaB.

    abstract::Nuclear factor-kappa B (NF-kappaB) plays an important role in UV-induced skin tumorigenesis. Activation of NF-kappaB by UV-irradiation is composed of two phases. The early phase culminates with maximal levels of DNA binding ability at 4 h postirradiation and is dependent on translational inhibition. The late-phase act...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2008.00385.x

    authors: László CF,Wu S

    更新日期:2008-11-01 00:00:00

  • Heat and concentration effects on the small heat shock protein, alpha-crystallin.

    abstract::alpha-Crystallin, a major protein of the mammalian lens, plays a vital role in maintaining the structural stability and transparency of the lens. It performs this function through chaperone-like activity; it has recently been reported that heating alpha-crystallin enhances this ability. The present studies, using both...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)071<0470:haceot>2.0.co;2

    authors: Mandal K,Dillon J,Gaillard ER

    更新日期:2000-04-01 00:00:00

  • Monitoring photoproduct formation and photobleaching by fluorescence spectroscopy has the potential to improve PDT dosimetry with a verteporfin-like photosensitizer.

    abstract::In current clinical practice, photodynamic therapy (PDT) is carried out with prescribed drug doses and light doses as well as fixed drug-light intervals and illumination fluence rates. This approach can result in undesirable treatment outcomes of either overtreatment or undertreatment because of biological variations ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2002)075<0398:mpfapb>2.0.co;2

    authors: Zeng H,Korbelik M,McLean DI,MacAulay C,Lui H

    更新日期:2002-04-01 00:00:00

  • Photobleaching of reduced nicotinamide adenine dinucleotide and the development of highly fluorescent lesions in rat basophilic leukemia cells during multiphoton microscopy.

    abstract::Endogenous reduced nicotinamide adenine dinucleotide (NADH) fluorescence provides an intrinsic indicator of the cellular metabolic state, but prolonged monitoring is limited by photobleaching and/or phototoxicity. Multiphoton excitation of NADH by ultrashort, 740-nm laser pulses provides a significant improvement over...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/2005-09-19-RA-689

    authors: Tiede LM,Nichols MG

    更新日期:2006-05-01 00:00:00

  • Empirical evaluation of a simple analytical formula for the ultraviolet index.

    abstract::This paper focuses on the estimation of the UV Index (UVI) for all sky conditions using a simple analytical parameterization involving three independent variables: the solar zenith angle, the total ozone column and the clearness index. Measurements of the UVI made at Badajoz and Cáceres (Southwestern Spain) from Janua...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2010.00860.x

    authors: Antón M,Serrano A,Cancillo ML,García JA,Madronich S

    更新日期:2011-03-01 00:00:00

  • Low-light-induced violaxanthin de-epoxidation in shortly preheated leaves: uncoupling from Delta pH-dependent nonphotochemical quenching.

    abstract::Plants protect themselves against excessive light by the induction of Delta pH-dependent nonphotochemical quenching (qE) that is associated with de-epoxidation of violaxanthin (V) to zeaxanthin (Z) in thylakoid membranes. In this work, we report that low light (12 micromol photons m(-2) s(-1)) is sufficient for a mark...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00699.x

    authors: Ilík P,Kotabová E,Spundová M,Novák O,Kana R,Strzałka K

    更新日期:2010-05-01 00:00:00

  • Effects of UV irradiation on skin and nonskin-associated herpes simplex virus infections in rats.

    abstract::Herpes simplex virus (HSV) normally causes vescular lesions on mucocutaneous surfaces but can also cause encephalitis. The virus can reactivate from the latent state in neurons to form recrudescent lesions. One common stimulus for reactivation is exposure to sunlight. In the present study, the effects of irradiating r...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)072<0645:eouios>2.0.co;2

    authors: Garssen J,van der Molen R,de Klerk A,Norval M,van Loveren H

    更新日期:2000-11-01 00:00:00

  • Spectroscopic properties of potential sensitizers for new photodynamic therapy start mechanisms via two-step excited electronic states.

    abstract::Three substituted tetraazaporphyrins, octa-(4-tert-butylphenyl)-tetrapyrazinoporphyrazine, tetra-(4-tert-butyl)phthalocyanine and tetra-(4-tert-butyl)phthalocyanatomagnesium(t4-PcMg), were spectroscopically checked in solutions and liposomes with respect to suitability as potential sensitizers of a possible new start ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.1993.tb02320.x

    authors: Teuchner K,Pfarrherr A,Stiel H,Freyer W,Leupold D

    更新日期:1993-03-01 00:00:00

  • Simplified categorization of outdoor activities for male and female U.S. indoor workers-a feasibility study to improve assessment of ultraviolet radiation exposures in epidemiologic study questionnaires.

    abstract::Skin cancer studies depend on questionnaires to estimate exposure to ultraviolet light and subsequent risk but are limited by recall bias. We investigate the feasibility of developing a short checklist of categories comprising outdoor activities that can improve sun exposure questionnaires for use in epidemiologic stu...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2008.00393.x

    authors: Kwok RK,Linet MS,Chodick G,Kleinerman RA,Freedman DM,Fears T,Johnson RE,Alexander BH

    更新日期:2009-01-01 00:00:00

  • Action spectra again?

    abstract::Action spectroscopy has a long history and is of central importance to photobiological studies. Action spectra were among the first assays to point to chlorophyll as the molecule most responsible for plant growth and to DNA as the genetic material. It is useful to construct action spectra early in the investigation of...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章,评审

    doi:10.1111/j.1751-1097.1991.tb02103.x

    authors: Coohill TP

    更新日期:1991-11-01 00:00:00

  • Why is rose bengal more phototoxic to fibroblasts in vitro than in vivo?

    abstract::Photosensitized protein cross-linking has been recently developed to seal wounds and strengthen tissue. Although the photosensitizing dye, Rose Bengal (RB), is phototoxic to cultured cells, cytotoxicity does not accompany RB-photosensitized tissue repair in vivo. We investigated whether the environment surrounding cel...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12215

    authors: Yao M,Gu C,Doyle FJ Jr,Zhu H,Redmond RW,Kochevar IE

    更新日期:2014-03-01 00:00:00

  • A Photoprotective Effect by Cation-π-Interaction? Quenching of Singlet Oxygen by an Indole Cation-π Model System.

    abstract::We investigated the effect of the cation-π interaction on the susceptibility of a tryptophan model system toward interaction with singlet oxygen, that is, type II photooxidation. The model system consists of two indole units linked to a lariat crown ether to measure the total rate of removal of singlet oxygen by the i...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13287

    authors: Arevalo GE,Cagan DA,Monsour CG,Garcia AC,McCurdy A,Selke M

    更新日期:2020-11-01 00:00:00

  • The Anthocyanins, Oenin and Callistephin, Protect RPE Cells Against Oxidative Stress.

    abstract::The retinal pigment epithelium (RPE) is a highly metabolic layer of postmitotic cells lining Bruch's membrane in the retina. While these cells contain endogenous photosensitizers that mediate blue light-induced damage, it has also been shown that blue light exposure damages mitochondrial DNA in RPE cells resulting in ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12683

    authors: Yacout SM,Gaillard ER

    更新日期:2017-03-01 00:00:00

  • Effects of short- and long-term ultraviolet B irradiation on the immune system of the common carp (Cyprinus carpio).

    abstract::Carp (Cyprinus carpio) were repeatedly exposed to 0, 60, 120 and 240 mJ/cm2 ultraviolet B (UVB) radiation three times in 1 week (short-term exposure) or 12 times in 4 weeks (long-term exposure). The effect of UVB on the functioning of the carp immune system was studied on day 2 after the final irradiation. After short...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/2004-07-13-RA-231

    authors: Markkula SE,Salo HM,Immonen AK,Jokinen EI

    更新日期:2005-05-01 00:00:00

  • Photochemical syn-anti isomerization reactions in N2-hydroxyisocytosines--an experimental matrix isolation and theoretical study.

    abstract::N2-hydroxyisocytosine and 1-methyl-N2-hydroxyisocytosine were studied using a matrix isolation technique combined with infrared absorption spectroscopy. For N2-hydroxyisocytosine isolated in an Ar matrix (at 10 K), two imino-oxo isomers, one with the hydroxyimino =N-OH group directed toward the N1-H group (the form ca...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2003)077<0243:psairi>2.0.co;2

    authors: Lapinski L,Nowak MJ,Kwiatkowski JS,Leszczynski J

    更新日期:2003-03-01 00:00:00

  • Ultraviolet A radiation induces rapid apoptosis of human leukemia cells by Fas ligand-independent activation of the Fas death pathways.

    abstract::Endogenous cellular chromophores absorb ultraviolet A radiation (UVA, 290-320 nm), the major UV component of terrestrial solar radiation, leading to the formation of reactive oxidizing species that initiate apoptosis, gene expression and mutagenesis. UVA-induced apoptosis of T helper cells is believed to underlie the ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2003)078<0061:uarira>2.0.co;2

    authors: Zhuang S,Kochevar IE

    更新日期:2003-07-01 00:00:00

  • Comparison of UV-absorbing nets in pepper crops: spectral properties, effects on plants and pest control.

    abstract::In horticultural crops, the use of screens to protect plants is the usual strategy in the Mediterranean area. Screen manufacturers offer a range of netting that vary in their UV-absorbing properties. We compared the photoeffects of seven different screens. Sweet pepper trials were conducted at the Gilat Research Cente...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00657.x

    authors: Legarrea S,Karnieli A,Fereres A,Weintraub PG

    更新日期:2010-03-01 00:00:00

  • Cloning and Characterization of Luciferase from the Chinese Firefly Lamprigera yunnana.

    abstract::Lamprigera (Lampyridae) is a small genus with only 17 species distributing in Asian countries. Its larviform females and alate males can produce continuously strong yellow-green light at night. However, no luciferase gene was reported for this genus and its subfamily-level phylogenetic position still remains uncertain...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13109

    authors: Liu GC,Zhang R,Hou QB,He JW,Dong ZW,Zhao RP,Wang W,Li XY

    更新日期:2019-09-01 00:00:00

  • Photophysics and photochemistry of z-chlorprothixene in acetonitrile.

    abstract::Chlorprothixene (CPTX, Taractan) is a low potency antipsychotic mainly used for the treatment of psychotic disorders (e.g. schizophrenia) and acute mania occurring as part of bipolar disorders. As in the case of other numerous drugs used in the treatment of psychiatric disorders, CPTX presents geometric isomerism. The...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00584.x

    authors: Piñero LE,García C,Lhiaubet-Vallet V,Oyola R,Miranda MA

    更新日期:2009-07-01 00:00:00

  • Phototaxis of Haloarcula marismortui revealed through a novel microbial motion analysis algorithm.

    abstract::Haloarcula marismortui has been described to be nonmotile prior to the recent identification of flagellar filaments, suggesting the motile nature of H. marismortui. Here we observed the locomotion of freshly cultured H. marismortui cells and tracked the swimming trajectories via ImageJ. Trajectories of H. marismortui ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2010.00768.x

    authors: Lin YC,Fu HY,Yang CS

    更新日期:2010-09-01 00:00:00

  • Resonance Raman and surface-enhanced resonance Raman spectra of LH2 antenna complex from Rhodobacter sphaeroides and Ectothiorhodospira sp. excited in the Qx and Qy transitions.

    abstract::Well-resolved vibrational spectra of LH2 complex isolated from two photosynthetic bacteria, Rhodobacter sphaeroides and Ectothiorhodospira sp., were obtained using surface-enhanced resonance Raman scattering (SERRS) exciting into the Qx and the Qy transitions of bacteriochlorophyll a. High-quality SERRS spectra in the...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2000)071<0589:rraser>2.0.co;2

    authors: Chumanov G,Picorel R,Ortiz de Zarate I,Cotton TM,Seibert M

    更新日期:2000-05-01 00:00:00

  • Photophysical properties of metal ion functionalized NaY zeolite.

    abstract::A series of luminescent ion exchanged zeolite are synthesized by introducing various ions into NaY zeolite. Monometal ion (Eu(3+), Tb(3+), Ce(3+), Y(3+), Zn(2+), Cd(2+), Cu(2+)) exchanged zeolite, rare-earth ion (Eu(3+), Tb(3+), Ce(3+)) exchanged zeolite modified with Y(3+) and rare-earth ion (Eu(3+), Tb(3+), Ce(3+)) ...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.12235

    authors: Duan TW,Yan B

    更新日期:2014-05-01 00:00:00

  • A Comparison of Solar Ultraviolet Radiation Exposure in Urban Canyons in Venice, Italy and Johannesburg, South Africa.

    abstract::Urban environments can have high-risk spaces that can provide excess personal sun exposure, such as urban or street canyons, and the spaces between buildings, among others. In these urban spaces, sun exposure can be high or low depending on several factors. Polysulphone film (PSF) was used to assess possible daily sol...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/php.13291

    authors: Wright CY,du Preez DJ,Martincigh BS,Allen MW,Millar DA,Wernecke B,Blesic S

    更新日期:2020-09-01 00:00:00

  • UVA exposure affects UVB and cis-urocanic acid-induced systemic suppression of immune responses in Listeria monocytogenes-infected Balb/c mice.

    abstract::Ultraviolet radiation can inhibit immune responses locally as well as systemically. Such effects have been measured in animals and humans exposed to ultraviolet B (wavelength 280-315 nm) (UVB) and ultraviolet A (315-400 nm) (UVA). The precise wavelength dependence is important for the identification of possible molecu...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/0031-8655(2001)073<0432:UEAUAC>2.0.CO;2

    authors: Garssen J,de Gruijl F,Mol D,de Klerk A,Roholl P,Van Loveren H

    更新日期:2001-04-01 00:00:00

  • Personal sun exposure and serum 25-hydroxy vitamin D concentrations.

    abstract::Solar ultraviolet-B radiation (UVB) is essential for epidermal vitamin D production. We aimed to quantitate the relationship between personal solar UV exposure and serum 25hydroxy vitamin D (25[OH]D) concentration. Blood was collected for 25(OH)D analysis in 207 South Australian adults aged 27-61 years. At the time of...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2012.01201.x

    authors: Nair-Shalliker V,Clements M,Fenech M,Armstrong BK

    更新日期:2013-01-01 00:00:00

  • Contact transcleral ciliary body photodynamic therapy with verteporfin in pigmented rabbits: effect of repeated treatments.

    abstract::We studied the effect on the intraocular pressure (IOP) and the ciliary body (CB) morphology after four consecutive contact transcleral photodynamic treatments of the ciliary body (CB-PDT) with verteporfin in pigmented rabbits. Twenty-two pigmented rabbits underwent CB-PDT (study group), performed once (six rabbits) o...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2009.00638.x

    authors: Charisis SK,Naoumidi II,Ginis HS,Detorakis ET,Tsilimbaris MK

    更新日期:2010-01-01 00:00:00

  • Effects of supplementary ultraviolet-B irradiance on maize yield and qualities: a field experiment.

    abstract::Stratospheric ozone depletion has caused an increase in the amount of ultraviolet-B (UV-B) radiation reaching the earth's surface. Numerous investigations have demonstrated that the effect of UV-B enhancements on plants includes reduction in grain yield, alteration in species competition, susceptibility to disease and...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1562/2004-05-03-RA-156.1

    authors: Gao W,Zheng Y,Slusser JR,Heisler GM,Grant RH,Xu J,He D

    更新日期:2004-07-01 00:00:00

  • Low-level laser therapy ameliorates CCl4-induced liver cirrhosis in rats.

    abstract::This study investigated the effects of low-level laser therapy (LLLT) in the liver function, structure and inflammation in a experimental model of carbon tetrachloride (CCl(4))-induced liver cirrhosis. Wistar rats were divided into Control, LLLT, CCl(4) and CCl(4) +LLLT groups. CCl(4) groups received CCl(4) (0.4 g kg(...

    journal_title:Photochemistry and photobiology

    pub_type: 杂志文章

    doi:10.1111/j.1751-1097.2012.01211.x

    authors: Oliveira-Junior MC,Monteiro AS,Leal-Junior EC,Munin E,Osório RA,Ribeiro W,Vieira RP

    更新日期:2013-01-01 00:00:00