Prediction of chemical residues in aquatic organisms for a field discharge situation.

Abstract:

:A field study was performed which compared predicted and measured concentrations of chemicals in receiving water organisms from three sampling locations on Five Mile Creek, Birmingham, Al. Two point source discharges, both from coke manufacturing facilities, were included in the field site and five chemicals were studied, i.e., biphenyl, phenanthrene, anthracene, fluoranthene, and pyrene. Composite samples of effluent, receiving water organisms, crayfish (Decapoda) and sunfish (Lepomis sp.), and stream and discharge flow data were collected in March and April 1990. For the crayfish and sunfish, the measured residues were within a factor of 5 for 80% (12 of 15) and 53% (8 of 15) of the residues predicted using EPA's draft procedure (US-EPA 199 lb), respectively, and were within a factor of 5 for 60% (9 of 15) and 40% (6 of 15) of the residues predicted using EPA's procedure with a BCF set equal to the chemical's Kow (after adjustment for lipid content of the organism), respectively. The predicted residues tended to be larger than the measured residues and with increasing Kow, greater disagreement between the predicted and measured values was observed.

journal_name

Chemosphere

journal_title

Chemosphere

authors

Burkhard LP,Sheedy BR,McCauley DJ

doi

10.1016/0045-6535(94)90096-5

subject

Has Abstract

pub_date

1994-07-01 00:00:00

pages

141-53

issue

1

eissn

0045-6535

issn

1879-1298

pii

0045-6535(94)90096-5

journal_volume

29

pub_type

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