Kinetics of the bio-oxidation of volatile reduced sulphur compounds in a biotrickling filter.

Abstract:

:Mixtures of volatile reduced sulphur compounds (VRSCs) like hydrogen sulphide (H(2)S), methylmercaptan (MM), dimethyl sulphide (DMS) and dimethyl disulphide (DMDS) are found in gaseous emissions of several industrial activities creating nuisance in the surroundings. Hydrogen sulphide (H(2)S) decreases the removal efficiency of volatile reduced sulphur compounds (VRSCs) in biofilters but the kinetics of this effect is still unknown. Kinetic expressions that represent the rate of bio-oxidation of H(2)S, MM, DMS and DMDS are proposed. In order to observe and quantify this effect, equimolar mixtures of MM, DMS and DMDS were fed into a biotrickling filter inoculated with Thiobacillus thioparus at different H(2)S loads. Experimental results shown a good agreement with the simulations generated by the model considering the kinetic equations proposed. The estimated kinetic constants show that H(2)S and MM have a significant inhibitory effect on the bio-oxidation of DMS and DMDS, having the H(2)S the higher effect.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Cáceres M,Silva J,Morales M,San Martín R,Aroca G

doi

10.1016/j.biortech.2012.04.039

subject

Has Abstract

pub_date

2012-08-01 00:00:00

pages

243-8

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(12)00644-X

journal_volume

118

pub_type

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