Rheological behavior and non-enzymatic degradation of a sulfated galactan from Halymenia durvillei (Halymeniales, Rhodophyta).

Abstract:

:The rheological behavior of a sulfated galactan extracted from Halymenia durvillei, a red seaweed collected in the coastal waters of a small island of Madagascar (Nosy-be in Indian Ocean), was investigated in dilute and semi-dilute solutions. In dilute solution with NaCl at 0.3 M, the polysaccharide adopted a coil conformation whereas, at higher concentrations, the polymer had the behavior of shear-thinning fluid, typical of polymer with high molar mass or semi-rigid conformation. Degradations of this lambda carrageenan-like, using radical depolymerization, and high-pressure homogenization led to several samples of various and controlled molar masses. The measure of their intrinsic viscosities permitted the determination of the relationship of Mark-Houwink-Sakurada.

authors

Fenoradosoa TA,Laroche C,Delattre C,Dulong V,Le Cerf D,Picton L,Michaud P

doi

10.1007/s12010-012-9605-z

subject

Has Abstract

pub_date

2012-07-01 00:00:00

pages

1303-13

issue

5

eissn

0273-2289

issn

1559-0291

journal_volume

167

pub_type

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