The influence of temperature and hydration on the sorption properties of bentonite.

Abstract:

:The effects of exposure to synthetic groundwater at elevated temperature gradients on the sorption properties of bentonite were investigated using the Mock-Up-Cz experiment. This experiment simulated the vertical placement of a container of radioactive waste according to the Swedish KBS-3 system for a period of more than 3 years. The mineralogical composition, as well as its chemical and physico-chemical properties, including the uptake of (99)TcO(4)(-) and (134)Cs(+), was used to evaluate the chemical changes caused by the long-term exposure of bentonite buffer to thermal and hydration gradients. It was found that the bentonite material was predominantly stable. No more than 2% of the montmorillonite was transformed due to thermal and moisture gradients. It was concluded that the new-formed mineral phases have no significant influence on the ion exchange and sorption properties of bulk bentonite samples.

journal_name

J Environ Radioact

authors

Vinsová H,Jedináková-Krízová V,Kolaríková I,Adamcová J,Prikryl R,Zeman J

doi

10.1016/j.jenvrad.2007.11.003

subject

Has Abstract

pub_date

2008-02-01 00:00:00

pages

415-25

issue

2

eissn

0265-931X

issn

1879-1700

pii

S0265-931X(07)00280-9

journal_volume

99

pub_type

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