Testing the behaviour of different kinetic models for uptake/release of radionuclides between water and sediments when implemented in a marine dispersion model.

Abstract:

:Three kinetic models for adsorption/release of (137)Cs between water and sediments have been tested when they are included in a previously validated dispersion model of the English Channel. Radionuclides are released to the Channel from La Hague nuclear fuel reprocessing plant (France). The kinetic models are a 1-step model consisting of a single reversible reaction, a 2-step model consisting of two consecutive reversible reactions and an irreversible model consisting of three parallel reactions: two reversible and one irreversible. The models have been tested under three typical situations that correspond to the source terms that can generally be found: instantaneous release, continuous release and redissolution of radionuclides from contaminated sediments. Differences between the models become more evident when contact times between water and sediments are larger (continuous release) and in the case of redissolution from sediments. Time scales for the redissolution process are rather different between the three models. The 1-step model produces a redissolution that is too fast when compared with experimental evidence. The irreversible model requires that saturation effects of the irreversible phase are included. Probably, the 2-step model represents the best compromise between ease and level of detail of the description of sorption/release processes.

journal_name

J Environ Radioact

authors

Periáñez R

doi

10.1016/S0265-931X(03)00172-3

subject

Has Abstract

pub_date

2004-01-01 00:00:00

pages

243-59

issue

3

eissn

0265-931X

issn

1879-1700

pii

S0265-931X(03)00172-3

journal_volume

71

pub_type

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