Abstract:
:The [Cu(sulfathiazolato)(2)(benzimidazole)(2)]2MeOH complex has been synthesised and characterised. It crystallises in the monoclinic system, space group C1c1, with unit cell dimensions a=18.829(7) A, b=12.206(3) A, c=17.233(5) A, alpha=90.06(2) degrees, beta=97.28(3) degrees, gamma=90.21(3) degrees and Z=4. The geometry around the copper(II) ion is intermediate between tetrahedral and square planar. The complex produces cleavage of plasmid pUC18 in presence of reducing agents. The efficiency of cleavage reaction of the title compound with pUC18 and with different reducing agents follows the order ascorbate-H(2)O(2)>ascorbate>MPA>dithiothreitol>H(2)O(2).
journal_name
J Inorg Biochemjournal_title
Journal of inorganic biochemistryauthors
González-Alvarez M,Alzuet G,Borrás J,Macías B,del Olmo M,Liu-González M,Sanz Fdoi
10.1016/s0162-0134(01)00369-5subject
Has Abstractpub_date
2002-04-10 00:00:00pages
29-35issue
1-2eissn
0162-0134issn
1873-3344pii
S0162013401003695journal_volume
89pub_type
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