First synthesis of a alpha-trifluoromethyl allenol ether via the Julia-Lythgoe process.

Abstract:

:Alpha-trifluoromethyl allenol ethers 9a-e were prepared in moderate to good yields by the Julia-Lythgoe process using beta-ethoxy-beta-trifluoromethyl vinylic sulfone 3. Several reactions of 9c were examined to give alpha,beta-unsaturated trifluoromethyl ketone derivatives 11 and 12.

authors

Yoshimatsu M,Hibino M

doi

10.1248/cpb.48.1395

subject

Has Abstract

pub_date

2000-09-01 00:00:00

pages

1395-8

issue

9

eissn

0009-2363

issn

1347-5223

journal_volume

48

pub_type

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