Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation.

Abstract:

:An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation-namely, Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point. However, neither model should be considered realistic for experimental adsorption systems.

authors

Hill TL

doi

10.1073/pnas.93.25.14328

subject

Has Abstract

pub_date

1996-12-10 00:00:00

pages

14328-32

issue

25

eissn

0027-8424

issn

1091-6490

journal_volume

93

pub_type

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