Application of gradient acid fractionation protocol to improve decolorization technology by lignin-based adsorbent.

Abstract:

:Wastewater contaminated with dyes is discharged by huge amount daily, and involved many hazardous materials. Thus, this study focused on introducing low cost, ecofriendly and available removal agent (lignin-based adsorbent). Three adsorbents, APKL-4, APKL-5 and APKL-6 were obtained using gradient acid precipitation technology and used for methylene blue (MB) removal. The samples were characterized by SEM, FT-IR and zeta potential analyzer. The results indicated that the three adsorbents exhibit significantly different adsorption behavior due to the structural differences caused by fractionation. The APKL-5 and APKL-6 have fewer hydrophilic groups in their molecules and thus have more adsorption active sites to load MB molecules. A pore structure inside of APKL-5 molecules is form in acid fractionation, which allows it to carry more MB molecules. The adsorption capacity of APKL-5 increased 3.8 times (from 345 to 1310 mg g-1) in the alkaline solution which showing excellent pH responsiveness. This paper presents a new promising approach for preparing high efficiency, low cost and eco-friendly adsorbents and builds a foundation for developing further applications of lignin-based adsorbents.

journal_name

Int J Biol Macromol

authors

Li H,Yuan Z,Shang X,Shang H,Liu J,Darwesh OM,Li C,Fang J

doi

10.1016/j.ijbiomac.2020.12.206

subject

Has Abstract

pub_date

2020-12-31 00:00:00

pages

10-18

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(20)35386-1

journal_volume

172

pub_type

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