Hydrothermal synthesis of novel 1-aminoperylene diimide/TiO2/MoS2 composite with enhanced photocatalytic activity.

Abstract:

:1-aminoperylene diimide/TiO2/MoS2 composite (NH2-PDI/TiO2/MoS2) with ordered structure was prepared by hydrothermal synthesis method. The composite was characterized by XRD, SEM, FTIR, XPS, BET, DRS, PL, EIS, Raman, photocurrent, and Mott-Schottky plots spectroscopy. The potential positions of the conduction and valence bands, and the band gap energy of the semiconductors were estimated. The composite exhibited higher photocatalytic activity compared with the mono-component systems. The apparent rate constants (k) were determined as 0.00616, 0.00352, 0.00738, 0.00517, 0.00752, and 0.00806 min-1 for TiO2, NH2-PDI, NH2-PDI/TiO2, MoS2, MoS2/TiO2, and NH2-PDI/TiO2/MoS2, respectively. The detection of radical scavengers confirmed that superoxide radicals, photogenerated holes, and photogenerated electrons were the main active substances for MB degradation. Between type II- heterojunction mechanism and Z-scheme mechanism, the latter could explain the enhanced photocatalytic activity of the composite better. The Z-scheme mechanism accumulates more electrons at CB level of NH2-PDI and hence generates more super oxide radicals.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Ma Y,Wang Y,Jiang T,Zhang F,Li X,Zhu Y

doi

10.1038/s41598-020-78894-y

subject

Has Abstract

pub_date

2020-12-15 00:00:00

pages

22005

issue

1

issn

2045-2322

pii

10.1038/s41598-020-78894-y

journal_volume

10

pub_type

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