Polydopamine-assisted grafting of chitosan on porous poly (L-lactic acid) electrospun membranes for adsorption of heavy metal ions.

Abstract:

:In this study, a versatile method for the manufacturing of chitosan-grafted porous poly (L-lactic acid) (P-PLLA) nanofibrous membrane by using polydopamine (PDA) as an intermediate layer has been developed. P-PLLA fibres were electrospun and collected as nano/micro fibrous membranes. Highly porous fibres could serve as a substrate for chitosan to adsorb heavy metal ions. Moreover, PDA was used to modify P-PLLA surface to increase the coating uniformity and stability of chitosan. Due to the very high surface area of P-PLLA membranes and abundant amine groups of both PDA and chitosan, the fabricated membranes were utilized as adsorbent for removal of copper (Cu2+) ions from the wastewater. The adsorption capability of Cu2+ ions was examined with respect to the PDA polymerization times, pH, initial metal ion concentration and time. Finally, the equilibrium adsorption data of chitosan-grafted membranes fitted well with the Langmuir isotherm with the maximum adsorption capacity of 270.27 mg/g.

journal_name

Int J Biol Macromol

authors

Zia Q,Tabassum M,Meng J,Xin Z,Gong H,Li J

doi

10.1016/j.ijbiomac.2020.11.101

subject

Has Abstract

pub_date

2021-01-15 00:00:00

pages

1479-1490

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(20)35026-1

journal_volume

167

pub_type

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