Abstract:
:We propose to minimize the sampling time for high-throughput measurements of powder X-ray diffraction (XRD) and X-ray absorption fine structure (XAFS) in synchrotron radiation. The conventional synchrotron radiation powder X-ray diffraction method requires filling of a capillary tube, but a structure-refining diffraction pattern could be obtained by transferring the crushed powder to a tape and rotating the cassette-tape tool by ±5° around the sample position. XAFS spectra could also be measured with the sample attached to the tape. The time required for sample preparation was greatly reduced, which made high-throughput experiments with powders in synchrotron radiation experiments more accessible.
journal_name
ACS Comb Scijournal_title
ACS combinatorial scienceauthors
Fujimoto K,Aimi A,Maruyama Sdoi
10.1021/acscombsci.0c00174subject
Has Abstractpub_date
2020-12-14 00:00:00pages
734-737issue
12eissn
2156-8952issn
2156-8944journal_volume
22pub_type
杂志文章abstract::An efficient, three-component strategy for the improved synthesis of multifunctionalized 6,7-dihydrobenzofuran-4(5H)-ones under microwave irradiation in ethyl alcohol within short periods has been established. The synthesized benzofuran-4(5H)-ones have been readily converted into polyfunctionalized cinnoline-4-carboxa...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/co5000097
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abstract::An expedient and metal-free synthetic protocol for construction of substituted quinolines has been developed from anilines and phenylacetaldehydes using imidazolium cation-based ionic liquids as the reaction medium. Mechanistic analysis indicated that the reaction occurs through C-C and C-N bond formation to produce i...
journal_title:ACS combinatorial science
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abstract::A combinatorial library having 66 different ternary compositions of Pd-Ir-Ce was prepared via the impregnation method to find the optimum ternary composition with the highest performance toward oxygen reduction reaction (ORR) in acid media. Its performance in ORR activity of the combinatorial array was evaluated throu...
journal_title:ACS combinatorial science
pub_type: 杂志文章
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.7b00019
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journal_title:ACS combinatorial science
pub_type: 杂志文章
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abstract::Adleman's illustration of molecular computing using DNA paved the way toward an entirely new direction of computing (Adleman, L. M. Science 1994, 266, 1021). The exponential time complex combinatorial problem on a traditional computer turns out to be a separation problem involving a polynomial number of steps in DNA c...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.9b00150
更新日期:2020-05-11 00:00:00
abstract::A one-bead one-compound (OBOC) library of peptide-based imaging agents was developed where a 19F-containing moiety was added onto the N-terminus of octamer peptides through copper-free click chemistry prior to screening of the library. This created a library of complete imaging agents that was screened against CXCR4, ...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.9b00146
更新日期:2020-03-09 00:00:00
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.5b00142
更新日期:2015-12-14 00:00:00
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journal_title:ACS combinatorial science
pub_type: 杂志文章
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.5b00155
更新日期:2016-08-08 00:00:00
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/co2000357
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abstract::A novel parallel medicinal chemistry (PMC)-enabled synthesis of 1H-pyrazolo[3,4-d]pyrimidines employing condensation of easily accessible N-pyrazolylamides and nitriles has been developed. The presented studies describe singleton and library enablements that allowed rapid generation of molecular diversity to examine C...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.7b00116
更新日期:2017-11-13 00:00:00
abstract::A one-pot, three-component synthesis of benzimidazole-linked thiazolidines from 2-cyanomethyl benzimidazole, iso-, isothio-, or isoselenocyanates and 1,2-dichloroethane is reported. Isolation of the key intermediate formed during the course of the reaction validates its mechanistic pathway. Under the same reaction con...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.9b00161
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abstract::A series of diverse polycyclic heterocycles containing spirooxindole, pyridine/thiophene, and pyrrolidine/pyrrolizidine/pyrrolothiazole rings have been synthesized through the 1,3-dipolar cycloaddition of azomethine ylides generated in situ by the condensation of dicarbonyl compounds (isatin or acenaphthenequinone) an...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/co500085t
更新日期:2014-09-08 00:00:00
abstract::A condition-based skeletal divergent synthesis was explored to achieve skeletal diversity in two component condensation reaction. Cyanomethyl benzimidazole was reacted with α-bromoketone under thermal conditions to furnish 2-aminofuranyl-benzimidazoles, while the same reaction afforded 3-cyano-benzopyrrolo-imidazoles ...
journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.7b00052
更新日期:2017-07-10 00:00:00
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journal_title:ACS combinatorial science
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doi:10.1021/acscombsci.5b00018
更新日期:2015-08-10 00:00:00
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.8b00084
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.5b00188
更新日期:2016-05-09 00:00:00
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
pub_type: 杂志文章
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journal_title:ACS combinatorial science
pub_type: 杂志文章
doi:10.1021/acscombsci.0c00133
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journal_title:ACS combinatorial science
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doi:10.1021/co500003p
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journal_title:ACS combinatorial science
pub_type: 信件
doi:10.1021/co200165j
更新日期:2012-04-09 00:00:00
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journal_title:ACS combinatorial science
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journal_title:ACS combinatorial science
pub_type: 杂志文章
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