Abstract:
:Naturally occurring thymine (TM) was incorporated into bacterial poly(3-hydroxybutyrate) (PHB) polyester to fabricate a novel and green biocomposite. Both 0.5% and 1% TM exhibit supernucleation effect on PHB, and crystallization kinetics suggests TM significantly increased Tc and Xc, and substantially shortened t1/2 of PHB. Epitaxial nucleation caused by a perfect crystal lattice matching between PHB and TM, was proposed to elucidate nucleation mechanism of PHB. Hydrogen bond interaction exists between CO, C-O-C groups of PHB and -CH3 (or -CH)/-NH- group of TM. TM interacted with CO group of PHB crystalline phase rather than that of amorphous one. In addition, two new IR crystalline bands assigned to C-O-C group of PHB appeared in the presence of TM, which arises from shift of two amorphous ones, respectively. TM enhanced onset thermal degradation temperature of PHB, mainly attributed to increased degree of crystallinity of PHB and flame retardance effect of TM.
journal_name
Int J Biol Macromoljournal_title
International journal of biological macromoleculesauthors
Ma H,Wei Z,Zhou S,Zhu H,Tang J,Yin J,Yue J,Yang Jdoi
10.1016/j.ijbiomac.2020.10.044subject
Has Abstractpub_date
2020-12-15 00:00:00pages
1562-1573issue
Pt Aeissn
0141-8130issn
1879-0003pii
S0141-8130(20)34672-9journal_volume
165pub_type
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