Synthesis of polypyrrole/nitrogen-doped porous carbon matrix composite as the electrode material for supercapacitors.

Abstract:

:Polypyrrole complex nitrogen-doped porous carbon matrix (PPy/N-PCM) was synthesized by a simple two-step method. Firstly, graphene oxide was prepared by the modified Hummers method. Secondly, Polypyrrole was compounded on the graphene oxide substrate, and the carbon matrix with a high specific surface area was obtained through high-temperature carbonization and KOH activation, and polypyrrole was used as a nitrogen source for the final nitrogen-doped composite material. The structure characterization of the carbon matrix and the final composite material shows that the carbon matrix surface has obvious porous structure, and the polypyrrole nanospheres grow uniformly on the porous carbon matrix surface. The electrochemical evaluation show that the prepared PPy/N-PCM has excellent supercapacitor performance, and its specific capacitance can reach 237.5 F g-1. When the current density reaches 10 A g-1, it has good cycle stability (the capacitance retention after 1000 charge and discharge is 88.53% of the initial capacitance value, which is better than pure PPy-60.76% and PPy/rGO-C-71.84%). The excellent capacitance performance, good-looking micro-morphology and simple synthesis method of the PPy/N-PCM provide the possibility for its commercialization.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Feng M,Lu W,Zhou Y,Zhen R,He H,Wang Y,Li C

doi

10.1038/s41598-020-72392-x

subject

Has Abstract

pub_date

2020-09-21 00:00:00

pages

15370

issue

1

issn

2045-2322

pii

10.1038/s41598-020-72392-x

journal_volume

10

pub_type

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