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Millimeters long super flexible Mn5Si3@SiO2 electrical nanocables applicable in harsh environments.

Abstract：

:Providing high performance electrical nano-interconnects for micro-nano electronics that are robust in harsh environments is highly demanded. Today, electrical nano-interconnects based on metallic nanowires, e.g. Ag and Cu, are limited by their positive physicochemical reactivity and ductility under large strain (i.e. irreversible dislocations and local necking-down elongation) at high temperatures or in strong oxidizing and acidic environments. Herein, to overcome these limitations, high-quality millimetre-sized soft manganese-based silicide (Mn5Si3@SiO2) nanowire nanocables are designed via a glassy Si-Mn-O matrix assisted growth. The proposed nanocables exhibit good electrical performance (resistivity of 1.28 to 3.84×10-6 Ωm and maximum current density 1.22 to 3.54×107 A cm-2) at temperatures higher than 317°C in air atmosphere, strongly acidic (HCl, PH=1.0) and oxidizing (H2O2, 10%) ambient, and under complex electric field. The proposed Mn5Si3@SiO2 nanocables, which withstand a strain of 16.7% free of failure, could be exploited for diverse applications in flexible electronics and complex wiring configurations.

journal_name

Nat Commun

journal_title

Nature communications

authors

Sun Y,Sun B,He J,Yang G,Wang C

doi

10.1038/s41467-019-14244-5

subject

Has Abstract

pub_date

2020-01-31 00:00:00

pages

647

issue

1

issn

2041-1723

pii

10.1038/s41467-019-14244-5

journal_volume

11

pub_type

杂志文章

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