2N+4-rule and an atlas of bulk optical resonances of zigzag graphene nanoribbons.

Abstract:

:Development of on-chip integrated carbon-based optoelectronic nanocircuits requires fast and non-invasive structural characterization of their building blocks. Recent advances in synthesis of single wall carbon nanotubes and graphene nanoribbons allow for their use as atomically precise building blocks. However, while cataloged experimental data are available for the structural characterization of carbon nanotubes, such an atlas is absent for graphene nanoribbons. Here we theoretically investigate the optical absorption resonances of armchair carbon nanotubes and zigzag graphene nanoribbons continuously spanning the tube (ribbon) transverse sizes from 0.5(0.4) nm to 8.1(12.8) nm. We show that the linear mapping is guaranteed between the tube and ribbon bulk resonance when the number of atoms in the tube unit cell is [Formula: see text], where [Formula: see text] is the number of atoms in the ribbon unit cell. Thus, an atlas of carbon nanotubes optical transitions can be mapped to an atlas of zigzag graphene nanoribbons.

journal_name

Nat Commun

journal_title

Nature communications

authors

Payod RB,Grassano D,Santos GNC,Levshov DI,Pulci O,Saroka VA

doi

10.1038/s41467-019-13728-8

subject

Has Abstract

pub_date

2020-01-03 00:00:00

pages

82

issue

1

issn

2041-1723

pii

10.1038/s41467-019-13728-8

journal_volume

11

pub_type

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