Abstract:
:As a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging. Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride. The oxidation process is confirmed by successful trifluoromethoxylation, 18O-trifluoromethoxylation, the observation of AgOCF3 species, and DFT calculations.
journal_name
Nat Communjournal_title
Nature communicationsauthors
Yu J,Lin JH,Yu D,Du R,Xiao JCdoi
10.1038/s41467-019-13359-zsubject
Has Abstractpub_date
2019-11-25 00:00:00pages
5362issue
1issn
2041-1723pii
10.1038/s41467-019-13359-zjournal_volume
10pub_type
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