Compositional boundary layers trigger liquid unmixing in a basaltic crystal mush.

Abstract:

:The separation of immiscible liquids has significant implications for magma evolution and the formation of magmatic ore deposits. We combine high-resolution imaging and electron probe microanalysis with the first use of atom probe tomography on tholeiitic basaltic glass from Hawaii, the Snake River Plain, and Iceland, to investigate the onset of unmixing of basaltic liquids into Fe-rich and Si-rich conjugates. We examine the relationships between unmixing and crystal growth, and the evolution of a nanoemulsion in a crystal mush. We identify the previously unrecognised role played by compositional boundary layers in promoting unmixing around growing crystals at melt-crystal interfaces. Our findings have important implications for the formation of immiscible liquid in a crystal mush, the interpretations of compositional zoning in crystals, and the role of liquid immiscibility in controlling magma physical properties.

journal_name

Nat Commun

journal_title

Nature communications

authors

Honour VC,Holness MB,Charlier B,Piazolo SC,Namur O,Prosa TJ,Martin I,Helz RT,Maclennan J,Jean MM

doi

10.1038/s41467-019-12694-5

subject

Has Abstract

pub_date

2019-10-23 00:00:00

pages

4821

issue

1

issn

2041-1723

pii

10.1038/s41467-019-12694-5

journal_volume

10

pub_type

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