Electronic structure of MAPbI3 and MAPbCl3: importance of band alignment.

Abstract:

:Since their first appearance, organic-inorganic perovskite absorbers have been capturing the attention of the scientific community. While high efficiency devices highlight the importance of band level alignment, very little is known on the origin of the strong n-doping character observed in the perovskite. Here, by means of a highly accurate photoemission study, we shed light on the energy alignment in perovskite-based devices. Our results suggest that the interaction with the substrate may be the driver for the observed doping in the perovskite samples.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Caputo M,Cefarin N,Radivo A,Demitri N,Gigli L,Plaisier JR,Panighel M,Di Santo G,Moretti S,Giglia A,Polentarutti M,De Angelis F,Mosconi E,Umari P,Tormen M,Goldoni A

doi

10.1038/s41598-019-50108-0

subject

Has Abstract

pub_date

2019-10-22 00:00:00

pages

15159

issue

1

issn

2045-2322

pii

10.1038/s41598-019-50108-0

journal_volume

9

pub_type

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