Identification of unexpected chemical contaminants in baby food coming from plastic packaging migration by high resolution accurate mass spectrometry.

Abstract:

:Plastic multilayers are widely used for baby food packaging. However, it is important to consider that migration of food contact materials (FCM) into the baby food can occur. The comprehensive identification of potential migrants, including intentionally added substances (IAS) and non-intentionally added substances (NIAS), is required to assess the safety of these packaging materials. In this study, high resolution accurate mass spectrometry (HRAMS) with a data-independent acquisition method of sequential mass windows enables the detection of substances with corresponding deconvoluted fragment mass spectra. The identification of unexpected migrants present in the food simulants and in real baby food was facilitated by filtering strategies and by an in-house library. This approach has allowed the identification of 42 migrants, including eight NIAS detected for the first time. Two oligomers were quantified by means of reference standard materials at concentration levels above 0.010 mg/kg, exceeding the maximum residue levels for baby food.

journal_name

Food Chem

journal_title

Food chemistry

authors

Bauer A,Jesús F,Gómez Ramos MJ,Lozano A,Fernández-Alba AR

doi

10.1016/j.foodchem.2019.05.105

subject

Has Abstract

pub_date

2019-10-15 00:00:00

pages

274-288

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(19)30908-2

journal_volume

295

pub_type

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