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Visible light-induced direct α C-H functionalization of alcohols.

Abstract：

:Considering the synthetic value of introducing active alcoholic hydroxyl group, developing C-H functionalization of alcohols is of significance. Herein, we present a photochemical method that under visible light irradiation, selectfluor can effectively promote the oxidative cross-coupling between alcohols and heteroarenes without the external photocatalysis, achieving the selective α sp3 C-H arylation of alcohol, even in the presence of ether. The N-F activation of selectfluor under blue LEDs irradiation is evidenced by electron paramagnetic resonance (EPR) study, which is the key process for the oxidative activation of α sp3 C-H alcohols. The observed reactivity may have significant implications for chemical transformations.

journal_name

Nat Commun

journal_title

Nature communications

authors

Niu L,Liu J,Liang XA,Wang S,Lei A

doi

10.1038/s41467-019-08413-9

subject

Has Abstract

pub_date

2019-01-28 00:00:00

pages

467

issue

1

issn

2041-1723

pii

10.1038/s41467-019-08413-9

journal_volume

10

pub_type

杂志文章

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