当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Gas-responsive porous magnet distinguishes the electron spin of molecular oxygen.

Gas-responsive porous magnet distinguishes the electron spin of molecular oxygen.

Abstract：

:Gas-sensing materials are becoming increasingly important in our society, requiring high sensitivity to differentiate similar gases like N2 and O2. For the design of such materials, the driving force of electronic host-guest interaction or host-framework changes during the sorption process has commonly been considered necessary; however, this work demonstrates the use of the magnetic characteristics intrinsic to the guest molecules for distinguishing between diamagnetic N2 and CO2 gases from paramagnetic O2 gas. While the uptake of N2 and CO2 leads to an increase in TC through ferrimagnetic behavior, the uptake of O2 results in an O2 pressure-dependent continuous phase change from a ferrimagnet to an antiferromagnet, eventually leading to a novel ferrimagnet with aligned O2 spins following application of a magnetic field. This chameleonic material, the first with switchable magnetism that can discriminate between similarly sized N2 and O2 gases, provides wide scope for new gas-responsive porous magnets.

journal_name

Nat Commun

journal_title

Nature communications

authors

Kosaka W,Liu Z,Zhang J,Sato Y,Hori A,Matsuda R,Kitagawa S,Miyasaka H

doi

10.1038/s41467-018-07889-1

subject

Has Abstract

pub_date

2018-12-21 00:00:00

pages

5420

issue

1

issn

2041-1723

pii

10.1038/s41467-018-07889-1

journal_volume

9

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Vimentin filaments interact with the actin cortex in mitosis allowing normal cell division.

    abstract：:The vimentin network displays remarkable plasticity to support basic cellular functions and reorganizes during cell division. Here, we show that in several cell types vimentin filaments redistribute to the cell cortex during mitosis, forming a robust framework interwoven with cortical actin and affecting its organizat...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12029-4

    authors： Duarte S,Viedma-Poyatos Á,Navarro-Carrasco E,Martínez AE,Pajares MA,Pérez-Sala D

    更新日期：2019-09-13 00:00:00

  • Direct observation of coordinated DNA movements on the nucleosome during chromatin remodelling.

    abstract：:ATP-dependent chromatin remodelling enzymes (remodellers) regulate DNA accessibility in eukaryotic genomes. Many remodellers reposition (slide) nucleosomes, however, how DNA is propagated around the histone octamer during this process is unclear. Here we examine the real-time coordination of remodeller-induced DNA mov...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09657-1

    authors： Sabantsev A,Levendosky RF,Zhuang X,Bowman GD,Deindl S

    更新日期：2019-04-12 00:00:00

  • Anti-quenching NIR-II molecular fluorophores for in vivo high-contrast imaging and pH sensing.

    abstract：:The contrast and sensitivity of in vivo fluorescence imaging has been revolutionized by molecular fluorophores operating in the second near-infrared window (NIR-II; 1000-1700 nm), but an ongoing challenge is the solvatochromism-caused quenching in aqueous solution for the long-wavelength absorbing fluorophores. Herein...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09043-x

    authors： Wang S,Fan Y,Li D,Sun C,Lei Z,Lu L,Wang T,Zhang F

    更新日期：2019-03-05 00:00:00

  • HDAC6 inhibition reverses axonal transport defects in motor neurons derived from FUS-ALS patients.

    abstract：:Amyotrophic lateral sclerosis (ALS) is a rapidly progressive neurodegenerative disorder due to selective loss of motor neurons (MNs). Mutations in the fused in sarcoma (FUS) gene can cause both juvenile and late onset ALS. We generated and characterized induced pluripotent stem cells (iPSCs) from ALS patients with dif...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00911-y

    authors： Guo W,Naujock M,Fumagalli L,Vandoorne T,Baatsen P,Boon R,Ordovás L,Patel A,Welters M,Vanwelden T,Geens N,Tricot T,Benoy V,Steyaert J,Lefebvre-Omar C,Boesmans W,Jarpe M,Sterneckert J,Wegner F,Petri S,Bohl D,Vande

    更新日期：2017-10-11 00:00:00

  • Urban areas as hotspots for bees and pollination but not a panacea for all insects.

    abstract：:Urbanisation is an important global driver of biodiversity change, negatively impacting some species groups whilst providing opportunities for others. Yet its impact on ecosystem services is poorly investigated. Here, using a replicated experimental design, we test how Central European cities impact flying insects and...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-14496-6

    authors： Theodorou P,Radzevičiūtė R,Lentendu G,Kahnt B,Husemann M,Bleidorn C,Settele J,Schweiger O,Grosse I,Wubet T,Murray TE,Paxton RJ

    更新日期：2020-01-29 00:00:00

  • Docking sites inside Cas9 for adenine base editing diversification and RNA off-target elimination.

    abstract：:Base editing tools with diversified editing scopes and minimized RNA off-target activities are required for broad applications. Nevertheless, current Streptococcus pyogenes Cas9 (SpCas9)-based adenine base editors (ABEs) with minimized RNA off-target activities display constrained editing scopes with efficient editing...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-19730-9

    authors： Li S,Yuan B,Cao J,Chen J,Chen J,Qiu J,Zhao XM,Wang X,Qiu Z,Cheng TL

    更新日期：2020-11-17 00:00:00

  • Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors.

    abstract：:The divalent carbene carbon centre in cyclic (alkyl)(amino)carbenes (CAACs) is known to exhibit transition-metal-like insertion into E-H σ-bonds (E = H, N, Si, B, P, C, O) with formation of new, strong C-E and C-H bonds. Although subsequent transformations of the products represent an attractive strategy for metal-fre...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08967-8

    authors： Oldroyd NL,Chitnis SS,Annibale VT,Arz MI,Sparkes HA,Manners I

    更新日期：2019-03-26 00:00:00

  • Rotator side chains trigger cooperative transition for shape and function memory effect in organic semiconductors.

    abstract：:Martensitic transition is a solid-state phase transition involving cooperative movement of atoms, mostly studied in metallurgy. The main characteristics are low transition barrier, ultrafast kinetics, and structural reversibility. They are rarely observed in molecular crystals, and hence the origin and mechanism are l...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02607-9

    authors： Chung H,Dudenko D,Zhang F,D'Avino G,Ruzié C,Richard A,Schweicher G,Cornil J,Beljonne D,Geerts Y,Diao Y

    更新日期：2018-01-18 00:00:00

  • Improving mass spectrometry analysis of protein structures with arginine-selective chemical cross-linkers.

    abstract：:Chemical cross-linking of proteins coupled with mass spectrometry analysis (CXMS) is widely used to study protein-protein interactions (PPI), protein structures, and even protein dynamics. However, structural information provided by CXMS is still limited, partly because most CXMS experiments use lysine-lysine (K-K) cr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11917-z

    authors： Jones AX,Cao Y,Tang YL,Wang JH,Ding YH,Tan H,Chen ZL,Fang RQ,Yin J,Chen RC,Zhu X,She Y,Huang N,Shao F,Ye K,Sun RX,He SM,Lei X,Dong MQ

    更新日期：2019-09-02 00:00:00

  • Amplitude mode in the planar triangular antiferromagnet Na0.9MnO2.

    abstract：:Amplitude modes arising from symmetry breaking in materials are of broad interest in condensed matter physics. These modes reflect an oscillation in the amplitude of a complex order parameter, yet are typically unstable and decay into oscillations of the order parameter's phase. This renders stable amplitude modes rar...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-04601-1

    authors： Dally RL,Zhao Y,Xu Z,Chisnell R,Stone MB,Lynn JW,Balents L,Wilson SD

    更新日期：2018-06-05 00:00:00

  • Massive yet grossly underestimated global costs of invasive insects.

    abstract：:Insects have presented human society with some of its greatest development challenges by spreading diseases, consuming crops and damaging infrastructure. Despite the massive human and financial toll of invasive insects, cost estimates of their impacts remain sporadic, spatially incomplete and of questionable quality. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12986

    authors： Bradshaw CJ,Leroy B,Bellard C,Roiz D,Albert C,Fournier A,Barbet-Massin M,Salles JM,Simard F,Courchamp F

    更新日期：2016-10-04 00:00:00

  • MreB polymers and curvature localization are enhanced by RodZ and predict E. coli's cylindrical uniformity.

    abstract：:The actin-like protein MreB has been proposed to coordinate the synthesis of the cell wall to determine cell shape in bacteria. MreB is preferentially localized to areas of the cell with specific curved geometries, avoiding the cell poles. It remains unclear whether MreB's curvature preference is regulated by addition...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05186-5

    authors： Bratton BP,Shaevitz JW,Gitai Z,Morgenstein RM

    更新日期：2018-07-18 00:00:00

  • Critical speeding-up in the magnetoelectric response of spin-ice near its monopole liquid-gas transition.

    abstract：:Competing interactions in the so-called spin-ice compounds stabilize a frustrated ground state with finite zero-point entropy and, interestingly, emergent magnetic monopole excitations. The properties of these monopoles are at the focus of recent research with particular emphasis on their quantum dynamics. It is predi...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5853

    authors： Grams CP,Valldor M,Garst M,Hemberger J

    更新日期：2014-09-04 00:00:00

  • A mechanistic theory for aquatic food chain length.

    abstract：:Multiple hypotheses propose an ostensibly disparate array of drivers of food chain length (FCL), with contradictory support from natural settings. Here we posit that the magnitude of vertical energy flux in food webs underlies several drivers of FCL. We show that rising energy flux fuels top-heavy biomass pyramids, pr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02157-0

    authors： Ward CL,McCann KS

    更新日期：2017-12-11 00:00:00

  • Deconvolution of Buparlisib's mechanism of action defines specific PI3K and tubulin inhibitors for therapeutic intervention.

    abstract：:BKM120 (Buparlisib) is one of the most advanced phosphoinositide 3-kinase (PI3K) inhibitors for the treatment of cancer, but it interferes as an off-target effect with microtubule polymerization. Here, we developed two chemical derivatives that differ from BKM120 by only one atom. We show that these minute changes sep...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14683

    authors： Bohnacker T,Prota AE,Beaufils F,Burke JE,Melone A,Inglis AJ,Rageot D,Sele AM,Cmiljanovic V,Cmiljanovic N,Bargsten K,Aher A,Akhmanova A,Díaz JF,Fabbro D,Zvelebil M,Williams RL,Steinmetz MO,Wymann MP

    更新日期：2017-03-09 00:00:00

  • Precision ultrasound sensing on a chip.

    abstract：:Ultrasound sensors have wide applications across science and technology. However, improved sensitivity is required for both miniaturisation and increased spatial resolution. Here, we introduce cavity optomechanical ultrasound sensing, where dual optical and mechanical resonances enhance the ultrasound signal. We achie...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-08038-4

    authors： Basiri-Esfahani S,Armin A,Forstner S,Bowen WP

    更新日期：2019-01-10 00:00:00

  • Mouse MRI shows brain areas relatively larger in males emerge before those larger in females.

    abstract：:Sex differences exist in behaviors, disease and neuropsychiatric disorders. Sexual dimorphisms however, have yet to be studied across the whole brain and across a comprehensive time course of postnatal development. Here, we use manganese-enhanced MRI (MEMRI) to longitudinally image male and female C57BL/6J mice across...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-04921-2

    authors： Qiu LR,Fernandes DJ,Szulc-Lerch KU,Dazai J,Nieman BJ,Turnbull DH,Foster JA,Palmert MR,Lerch JP

    更新日期：2018-07-05 00:00:00

  • Late Na(+) current and protracted electrical recovery are critical determinants of the aging myopathy.

    abstract：:The aging myopathy manifests itself with diastolic dysfunction and preserved ejection fraction. We raised the possibility that, in a mouse model of physiological aging, defects in electromechanical properties of cardiomyocytes are important determinants of the diastolic characteristics of the myocardium, independently...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms9803

    authors： Signore S,Sorrentino A,Borghetti G,Cannata A,Meo M,Zhou Y,Kannappan R,Pasqualini F,O'Malley H,Sundman M,Tsigkas N,Zhang E,Arranto C,Mangiaracina C,Isobe K,Sena BF,Kim J,Goichberg P,Nahrendorf M,Isom LL,Leri A,An

    更新日期：2015-11-06 00:00:00

  • Printable enzyme-embedded materials for methane to methanol conversion.

    abstract：:An industrial process for the selective activation of methane under mild conditions would be highly valuable for controlling emissions to the environment and for utilizing vast new sources of natural gas. The only selective catalysts for methane activation and conversion to methanol under mild conditions are methane m...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11900

    authors： Blanchette CD,Knipe JM,Stolaroff JK,DeOtte JR,Oakdale JS,Maiti A,Lenhardt JM,Sirajuddin S,Rosenzweig AC,Baker SE

    更新日期：2016-06-15 00:00:00

  • Active acetylcholine receptors prevent the atrophy of skeletal muscles and favor reinnervation.

    abstract：:Denervation of skeletal muscles induces severe muscle atrophy, which is preceded by cellular alterations such as increased plasma membrane permeability, reduced resting membrane potential and accelerated protein catabolism. The factors that induce these changes remain unknown. Conversely, functional recovery following...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-14063-8

    authors： Cisterna BA,Vargas AA,Puebla C,Fernández P,Escamilla R,Lagos CF,Matus MF,Vilos C,Cea LA,Barnafi E,Gaete H,Escobar DF,Cardozo CP,Sáez JC

    更新日期：2020-02-26 00:00:00

  • Publisher Correction: A downy mildew effector evades recognition by polymorphism of expression and subcellular localization.

    abstract：:The original version of this article contained an error in the author affiliations. Oliver J. Furzer was incorrectly associated with Department of Plant Sciences, College of Life Sciences, Wuhan University, 430072, Wuhan, China.This has now been corrected in the HTML version of the article. The PDF version of the arti...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-018-08095-9

    authors： Asai S,Furzer OJ,Cevik V,Kim DS,Ishaque N,Goritschnig S,Staskawicz BJ,Shirasu K,Jones JDG

    更新日期：2019-01-08 00:00:00

  • In situ structures of rotavirus polymerase in action and mechanism of mRNA transcription and release.

    abstract：:Transcribing and replicating a double-stranded genome require protein modules to unwind, transcribe/replicate nucleic acid substrates, and release products. Here we present in situ cryo-electron microscopy structures of rotavirus dsRNA-dependent RNA polymerase (RdRp) in two states pertaining to transcription. In addit...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10236-7

    authors： Ding K,Celma CC,Zhang X,Chang T,Shen W,Atanasov I,Roy P,Zhou ZH

    更新日期：2019-05-17 00:00:00

  • ABL1 regulates spindle orientation in adherent cells and mammalian skin.

    abstract：:Despite the growing evidence for the regulated spindle orientation in mammals, a systematic approach for identifying the responsible genes in mammalian cells has not been established. Here we perform a kinase-targeting RNAi screen in HeLa cells and identify ABL1 as a novel regulator of spindle orientation. Knockdown o...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1634

    authors： Matsumura S,Hamasaki M,Yamamoto T,Ebisuya M,Sato M,Nishida E,Toyoshima F

    更新日期：2012-01-17 00:00:00

  • Free choice shapes normalized value signals in medial orbitofrontal cortex.

    abstract：:Normalization is a common cortical computation widely observed in sensory perception, but its importance in perception of reward value and decision making remains largely unknown. We examined (1) whether normalized value signals occur in the orbitofrontal cortex (OFC) and (2) whether changes in behavioral task context...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02614-w

    authors： Yamada H,Louie K,Tymula A,Glimcher PW

    更新日期：2018-01-11 00:00:00

  • Unraveling quantum pathways using optical 3D Fourier-transform spectroscopy.

    abstract：:Predicting and controlling quantum mechanical phenomena require knowledge of the system Hamiltonian. A detailed understanding of the quantum pathways used to construct the Hamiltonian is essential for deterministic control and improved performance of coherent control schemes. In complex systems, parameters characteriz...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2405

    authors： Li H,Bristow AD,Siemens ME,Moody G,Cundiff ST

    更新日期：2013-01-01 00:00:00

  • Quantifying gravity wave forcing using scale invariance.

    abstract：:Despite the increasing resolution, forcing on the mean circulation by resolved waves in general circulation models is not yet converging. Parameterization of the forcing remains a major source of model uncertainty. This study examines the scale invariance of zonal spectra of momentum flux and wave forcing, and shows t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10527-z

    authors： Liu HL

    更新日期：2019-06-13 00:00:00

  • Integrating single-cobalt-site and electric field of boron nitride in dechlorination electrocatalysts by bioinspired design.

    abstract：:The construction of enzyme-inspired artificial catalysts with enzyme-like active sites and microenvironment remains a great challenge. Herein, we report a single-atomic-site Co catalyst supported by carbon doped boron nitride (BCN) with locally polarized B-N bonds (Co SAs/BCN) to simulate the reductive dehalogenases. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-20619-w

    authors： Min Y,Zhou X,Chen JJ,Chen W,Zhou F,Wang Z,Yang J,Xiong C,Wang Y,Li F,Yu HQ,Wu Y

    更新日期：2021-01-12 00:00:00

  • Selective photocatalytic conversion of methane into carbon monoxide over zinc-heteropolyacid-titania nanocomposites.

    abstract：:Chemical utilization of vast fossil and renewable feedstocks of methane remains one of the most important challenges of modern chemistry. Herein, we report direct and selective methane photocatalytic oxidation at ambient conditions into carbon monoxide, which is an important chemical intermediate and a platform molecu...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08525-2

    authors： Yu X,De Waele V,Löfberg A,Ordomsky V,Khodakov AY

    更新日期：2019-02-11 00:00:00

  • Essential role of FBXL5-mediated cellular iron homeostasis in maintenance of hematopoietic stem cells.

    abstract：:Hematopoietic stem cells (HSCs) are maintained in a hypoxic niche to limit oxidative stress. Although iron elicits oxidative stress, the importance of iron homeostasis in HSCs has been unknown. Here we show that iron regulation by the F-box protein FBXL5 is required for HSC self-renewal. Conditional deletion of Fbxl5 ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms16114

    authors： Muto Y,Nishiyama M,Nita A,Moroishi T,Nakayama KI

    更新日期：2017-07-17 00:00:00

  • Coarse-grained simulation reveals key features of HIV-1 capsid self-assembly.

    abstract：:The maturation of HIV-1 viral particles is essential for viral infectivity. During maturation, many copies of the capsid protein (CA) self-assemble into a capsid shell to enclose the viral RNA. The mechanistic details of the initiation and early stages of capsid assembly remain to be delineated. We present coarse-grai...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11568

    authors： Grime JMA,Dama JF,Ganser-Pornillos BK,Woodward CL,Jensen GJ,Yeager M,Voth GA

    更新日期：2016-05-13 00:00:00