Mechanical properties improvement of thermoplastic corn starch and polyethylene-grafted-maleicanhydride blending by Na+ ions neutralization of carboxymethyl cellulose.

Abstract:

:Corn starch was melt-blended with glycerol (70/30) to prepare thermoplastic starch (TPS) at 140 °C for 10 min. The TPS was melt-blended with polyethylene grafted with maleic anhydride (PE-MAH) and carboxymethyl cellulose (CMC) to improve the properties of the TPS. Phase determination analysis and SEM images demonstrated that the morphology of the TPS/PE-MAH/CMC blend consisted of PE-MAH particles dispersed in the TPS matrix. The tensile strength and elongation were found to have improved with the addition of CMC 5 wt%. Adhesion between the polymers was observed by the asymmetric double-cantilever beam (ADCB) method. The PE-MAH/(TPS + CMC) sample showed high fracture toughness (Gc), which is related to the adhesion energy between the two polymers. This is suggestive of interactions between the MAH groups of PE-MAH and CMC. FT-IR results indicated that the neutralization and aggregation were formed by Na+ ions of CMC and the MAH of PE-MAH, which increased the interfacial adhesion between TPS and PE-MAH blend. The improvement in the mechanical properties of the TPS/PE-MAH/CMC blend is concluded to be because of the increase in the interfacial adhesion between TPS and PE-MAH by these neutralization and aggregation processes.

journal_name

Int J Biol Macromol

authors

Jantanasakulwong K,Wongsuriyasak S,Rachtanapun P,Seesuriyachan P,Chaiyaso T,Leksawasdi N,Techapun C

doi

10.1016/j.ijbiomac.2018.08.076

subject

Has Abstract

pub_date

2018-12-01 00:00:00

pages

297-301

issue

Pt A

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(18)33149-0

journal_volume

120

pub_type

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