Effect of plasticizers on microstructure, compatibility and mechanical property of hydroxypropyl methylcellulose/hydroxypropyl starch blends.

Abstract:

:Polymer film blends of hydroxypropyl methylcellulose (HPMC) and hydroxypropyl starch (HPS) were produced with an incorporation of three different plasticizers, including polyethylene glycol (PEG), glycerol and 1, 2-propylene glycol (PG) respectively, and the influence of these plasticizers were compared and studied by X-ray Diffraction (XRD), small angel X-ray Scattering (SAXS), optical microscope and dynamic mechanical analysis (DMA). Results showed that multi-scale structure of the blends were greatly affected by the plasticizers and therefore caused significant changes in mechanical properties. In the course, blends with glycerol presented lamellar structure rather than self-similar structure. Moreover, crystalline degree was increased with an order of glycerol > PEG > PG, whereas the compactness of amorphous region of all samples was decreased by PEG and PG.

journal_name

Int J Biol Macromol

authors

Zhang L,Wang XF,Liu H,Yu L,Wang Y,Simon GP,Qian J

doi

10.1016/j.ijbiomac.2018.07.064

subject

Has Abstract

pub_date

2018-11-01 00:00:00

pages

141-148

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(18)31871-3

journal_volume

119

pub_type

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