Single Crystal Organic Nanoflowers.

Abstract:

:Nano-flowers reported so far were mostly constituted of inorganic or hybrid materials. We have synthesized and crystallized a new organic compound, 1, 2-bis(tritylthio)ethane forming an organic nano-flower consisting of single crystalline petals. Crystal structure at nano and micro level indicates that π-π stacking interactions between aromatic systems is the principal factor governing molecular recognition and assembly. Single crystal X-ray Diffraction (S-XRD) supported by Selective Area Electron Diffraction (SAED) experiments indicate the single crystalline nature of the flower-like assembly even at the nanoscale. In order to fabricate the nanoflower as a potential stimulus responsive material; the 'petals' were coated with magnetite nanoparticles, verified by Energy-dispersive X-ray spectroscopic (EDX) analysis. Herein, we have further tested the potential utility of the hybrid material in water remediation as a nano-based adsorbent for removal of heavy metals like chromium.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Sasidharan S,P C S,Chaudhary N,Ramakrishnan V

doi

10.1038/s41598-017-17538-0

subject

Has Abstract

pub_date

2017-12-11 00:00:00

pages

17335

issue

1

issn

2045-2322

pii

10.1038/s41598-017-17538-0

journal_volume

7

pub_type

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