当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater.

Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater.

Abstract：

:Amidoxime-functionalized polymeric adsorbents are the current state-of-the-art materials for collecting uranium (U) from seawater. However, marine tests show that vanadium (V) is preferentially extracted over U and many other cations. Herein, we report a complementary and comprehensive investigation integrating ab initio simulations with thermochemical titrations and XAFS spectroscopy to understand the unusually strong and selective binding of V by polyamidoximes. While the open-chain amidoxime functionalities do not bind V, the cyclic imide-dioxime group of the adsorbent forms a peculiar non-oxido V5+ complex, exhibiting the highest stability constant value ever observed for the V5+ species. XAFS analysis of adsorbents following deployment in environmental seawater confirms V binding solely by the imide-dioximes. Our fundamental findings offer not only guidance for future optimization of selectivity in amidoxime-based sorbent materials, but may also afford insight to understanding the extensive accumulation of V in some marine organisms.

journal_name

Nat Commun

journal_title

Nature communications

authors

Ivanov AS,Leggett CJ,Parker BF,Zhang Z,Arnold J,Dai S,Abney CW,Bryantsev VS,Rao L

doi

10.1038/s41467-017-01443-1

subject

Has Abstract

pub_date

2017-11-16 00:00:00

pages

1560

issue

1

issn

2041-1723

pii

10.1038/s41467-017-01443-1

journal_volume

8

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Disruption of astrocyte-vascular coupling and the blood-brain barrier by invading glioma cells.

    abstract：:Astrocytic endfeet cover the entire cerebral vasculature and serve as exchange sites for ions, metabolites and energy substrates from the blood to the brain. They maintain endothelial tight junctions that form the blood-brain barrier (BBB) and release vasoactive molecules that regulate vascular tone. Malignant gliomas...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5196

    authors： Watkins S,Robel S,Kimbrough IF,Robert SM,Ellis-Davies G,Sontheimer H

    更新日期：2014-06-19 00:00:00

  • Impaired peroxisomal import in Drosophila oenocytes causes cardiac dysfunction by inducing upd3 as a peroxikine.

    abstract：:Aging is characterized by a chronic, low-grade inflammation, which is a major risk factor for cardiovascular diseases. It remains poorly understood whether pro-inflammatory factors released from non-cardiac tissues contribute to the non-autonomous regulation of age-related cardiac dysfunction. Here, we report that age...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-16781-w

    authors： Huang K,Miao T,Chang K,Kim J,Kang P,Jiang Q,Simmonds AJ,Di Cara F,Bai H

    更新日期：2020-06-10 00:00:00

  • The mechanistic and functional profile of the therapeutic anti-IgE antibody ligelizumab differs from omalizumab.

    abstract：:Targeting of immunoglobulin E (IgE) represents an interesting approach for the treatment of allergic disorders. A high-affinity monoclonal anti-IgE antibody, ligelizumab, has recently been developed to overcome some of the limitations associated with the clinical use of the therapeutic anti-IgE antibody, omalizumab. H...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-13815-w

    authors： Gasser P,Tarchevskaya SS,Guntern P,Brigger D,Ruppli R,Zbären N,Kleinboelting S,Heusser C,Jardetzky TS,Eggel A

    更新日期：2020-01-08 00:00:00

  • Multiple truncated isoforms of MAVS prevent its spontaneous aggregation in antiviral innate immune signalling.

    abstract：:In response to virus infection, RIG-I-like receptors (RLRs) sense virus RNA and induce MAVS to form prion-like aggregates to further propagate antiviral signalling. Although monomeric MAVS recombinant protein can assemble into prion-like filaments spontaneously in vitro, endogenous MAVS in cells is prevented from aggr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15676

    authors： Qi N,Shi Y,Zhang R,Zhu W,Yuan B,Li X,Wang C,Zhang X,Hou F

    更新日期：2017-06-13 00:00:00

  • Single cell analysis of human foetal liver captures the transcriptional profile of hepatobiliary hybrid progenitors.

    abstract：:The liver parenchyma is composed of hepatocytes and bile duct epithelial cells (BECs). Controversy exists regarding the cellular origin of human liver parenchymal tissue generation during embryonic development, homeostasis or repair. Here we report the existence of a hepatobiliary hybrid progenitor (HHyP) population i...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11266-x

    authors： Segal JM,Kent D,Wesche DJ,Ng SS,Serra M,Oulès B,Kar G,Emerton G,Blackford SJI,Darmanis S,Miquel R,Luong TV,Yamamoto R,Bonham A,Jassem W,Heaton N,Vigilante A,King A,Sancho R,Teichmann S,Quake SR,Nakauchi H,Rash

    更新日期：2019-07-26 00:00:00

  • Harnessing strong metal-support interactions via a reverse route.

    abstract：:Engineering strong metal-support interactions (SMSI) is an effective strategy for tuning structures and performances of supported metal catalysts but induces poor exposure of active sites. Here, we demonstrate a strong metal-support interaction via a reverse route (SMSIR) by starting from the final morphology of SMSI ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-16674-y

    authors： Wu P,Tan S,Moon J,Yan Z,Fung V,Li N,Yang SZ,Cheng Y,Abney CW,Wu Z,Savara A,Momen AM,Jiang DE,Su D,Li H,Zhu W,Dai S,Zhu H

    更新日期：2020-06-16 00:00:00

  • Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase.

    abstract：:FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, the inability to accumulate these intermediates in solution has thus far prevented their spectroscopic and c...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08668-2

    authors： Borrell M,Andris E,Navrátil R,Roithová J,Costas M

    更新日期：2019-02-22 00:00:00

  • Modular coherent photonic-aided payload receiver for communications satellites.

    abstract：:Ubiquitous satellite communications are in a leading position for bridging the digital divide. Fulfilling such a mission will require satellite services on par with fibre services, both in bandwidth and cost. Achieving such a performance requires a new generation of communications payloads powered by large-scale proce...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10077-4

    authors： Duarte VC,Prata JG,Ribeiro CF,Nogueira RN,Winzer G,Zimmermann L,Walker R,Clements S,Filipowicz M,Napierała M,Nasiłowski T,Crabb J,Kechagias M,Stampoulidis L,Anzalchi J,Drummond MV

    更新日期：2019-04-30 00:00:00

  • Nuclear retention of the transcription factor NLP7 orchestrates the early response to nitrate in plants.

    abstract：:Nitrate is both an important nutrient and a signalling molecule for plants. Although several components of the nitrate signalling pathway have been identified, their hierarchical organization remains unclear. Here we show that the localization of NLP7, a member of the RWP-RK transcription factor family, is regulated b...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2650

    authors： Marchive C,Roudier F,Castaings L,Bréhaut V,Blondet E,Colot V,Meyer C,Krapp A

    更新日期：2013-01-01 00:00:00

  • Dimensional and temporal controls of three-dimensional cell migration by zyxin and binding partners.

    abstract：:Spontaneous molecular oscillations are ubiquitous in biology. But to our knowledge, periodic cell migratory patterns have not been observed. Here we report the highly regular, periodic migration of cells along rectilinear tracks generated inside three-dimensional matrices, with each excursion encompassing several cell...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1711

    authors： Fraley SI,Feng Y,Giri A,Longmore GD,Wirtz D

    更新日期：2012-03-06 00:00:00

  • Observation of a new superfluid phase for 3He embedded in nematically ordered aerogel.

    abstract：:In bulk superfluid 3He at zero magnetic field, two phases emerge with the B-phase stable everywhere except at high pressures and temperatures, where the A-phase is favoured. Aerogels with nanostructure smaller than the superfluid coherence length are the only means to introduce disorder into the superfluid. Here we us...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12975

    authors： Zhelev N,Reichl M,Abhilash TS,Smith EN,Nguyen KX,Mueller EJ,Parpia JM

    更新日期：2016-09-27 00:00:00

  • Interface dominated cooperative nanoprecipitation in interstitial alloys.

    abstract：:Steels belong to one of the best established materials, however, the mechanisms of various phase transformations down to the nano length scale are still not fully clear. In this work, high-resolution transmission electron microscopy is combined with atomistic simulations to study the nanoscale carbide precipitation in...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06474-w

    authors： Wang H,Zhang X,Yan D,Somsen C,Eggeler G

    更新日期：2018-10-01 00:00:00

  • CXCR3 enables recruitment and site-specific bystander activation of memory CD8+ T cells.

    abstract：:Bystander activation of memory T cells occurs in the absence of cognate antigen during infections that elicit strong systemic inflammatory responses, which subsequently affect host immune responses. Here we report that memory T cell bystander activation is not limited to induction by systemic inflammation. We initiall...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12980-2

    authors： Maurice NJ,McElrath MJ,Andersen-Nissen E,Frahm N,Prlic M

    更新日期：2019-11-01 00:00:00

  • Highly efficient eco-friendly X-ray scintillators based on an organic manganese halide.

    abstract：:Scintillation based X-ray detection has received great attention for its application in a wide range of areas from security to healthcare. Here, we report highly efficient X-ray scintillators with state-of-the-art performance based on an organic metal halide, ethylenebis-triphenylphosphonium manganese (II) bromide ((C...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18119-y

    authors： Xu LJ,Lin X,He Q,Worku M,Ma B

    更新日期：2020-08-28 00:00:00

  • Low-dose penicillin in early life induces long-term changes in murine gut microbiota, brain cytokines and behavior.

    abstract：:There is increasing concern about potential long-term effects of antibiotics on children's health. Epidemiological studies have revealed that early-life antibiotic exposure can increase the risk of developing immune and metabolic diseases, and rodent studies have shown that administration of high doses of antibiotics ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15062

    authors： Leclercq S,Mian FM,Stanisz AM,Bindels LB,Cambier E,Ben-Amram H,Koren O,Forsythe P,Bienenstock J

    更新日期：2017-04-04 00:00:00

  • Integrative functional genomics decodes herpes simplex virus 1.

    abstract：:The predicted 80 open reading frames (ORFs) of herpes simplex virus 1 (HSV-1) have been intensively studied for decades. Here, we unravel the complete viral transcriptome and translatome during lytic infection with base-pair resolution by computational integration of multi-omics data. We identify a total of 201 transc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15992-5

    authors： Whisnant AW,Jürges CS,Hennig T,Wyler E,Prusty B,Rutkowski AJ,L'hernault A,Djakovic L,Göbel M,Döring K,Menegatti J,Antrobus R,Matheson NJ,Künzig FWH,Mastrobuoni G,Bielow C,Kempa S,Liang C,Dandekar T,Zimmer R,Landth

    更新日期：2020-04-27 00:00:00

  • Magneto-nanosensor platform for probing low-affinity protein-protein interactions and identification of a low-affinity PD-L1/PD-L2 interaction.

    abstract：:Substantial efforts have been made to understand the interactions between immune checkpoint receptors and their ligands targeted in immunotherapies against cancer. To carefully characterize the complete network of interactions involved and the binding affinities between their extracellular domains, an improved kinetic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12220

    authors： Lee JR,Bechstein DJ,Ooi CC,Patel A,Gaster RS,Ng E,Gonzalez LC,Wang SX

    更新日期：2016-07-22 00:00:00

  • FAK-heterozygous mice display enhanced tumour angiogenesis.

    abstract：:Genetic ablation of endothelial focal adhesion kinase (FAK) can inhibit pathological angiogenesis, suggesting that loss of endothelial FAK is sufficient to reduce neovascularization. Here we show that reduced stromal FAK expression in FAK-heterozygous mice unexpectedly enhances both B16F0 and CMT19T tumour growth and ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms3020

    authors： Kostourou V,Lechertier T,Reynolds LE,Lees DM,Baker M,Jones DT,Tavora B,Ramjaun AR,Birdsey GM,Robinson SD,Parsons M,Randi AM,Hart IR,Hodivala-Dilke K

    更新日期：2013-01-01 00:00:00

  • Experimental observation of anomalous topological edge modes in a slowly driven photonic lattice.

    abstract：:Topological quantum matter can be realized by subjecting engineered systems to time-periodic modulations. In analogy with static systems, periodically driven quantum matter can be topologically classified by topological invariants, whose non-zero value guarantees the presence of robust edge modes. In the high-frequenc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms13918

    authors： Mukherjee S,Spracklen A,Valiente M,Andersson E,Öhberg P,Goldman N,Thomson RR

    更新日期：2017-01-04 00:00:00

  • The telomere binding protein Pot1 maintains haematopoietic stem cell activity with age.

    abstract：:Repeated cell divisions and aging impair stem cell function. However, the mechanisms by which this occurs are not fully understood. Here we show that protection of telomeres 1A (Pot1a), a component of the Shelterin complex that protects telomeres, improves haematopoietic stem cell (HSC) activity during aging. Pot1a is...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00935-4

    authors： Hosokawa K,MacArthur BD,Ikushima YM,Toyama H,Masuhiro Y,Hanazawa S,Suda T,Arai F

    更新日期：2017-10-06 00:00:00

  • Synapse microarray identification of small molecules that enhance synaptogenesis.

    abstract：:Synaptic function is affected in many brain diseases and disorders. Technologies for large-scale synapse assays can facilitate identification of drug leads. Here we report a 'synapse microarray' technology that enables ultra-sensitive, high-throughput and quantitative screening of synaptogenesis. Our platform enables ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1518

    authors： Shi P,Scott MA,Ghosh B,Wan D,Wissner-Gross Z,Mazitschek R,Haggarty SJ,Yanik MF

    更新日期：2011-10-25 00:00:00

  • Elucidation of the biosynthesis of carnosic acid and its reconstitution in yeast.

    abstract：:Rosemary extracts containing the phenolic diterpenes carnosic acid and its derivative carnosol are approved food additives used in an increasingly wide range of products to enhance shelf-life, thanks to their high anti-oxidant activity. We describe here the elucidation of the complete biosynthetic pathway of carnosic ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12942

    authors： Scheler U,Brandt W,Porzel A,Rothe K,Manzano D,Božić D,Papaefthimiou D,Balcke GU,Henning A,Lohse S,Marillonnet S,Kanellis AK,Ferrer A,Tissier A

    更新日期：2016-10-05 00:00:00

  • Ventral midbrain stimulation induces perceptual learning and cortical plasticity in primates.

    abstract：:Practice improves perception and enhances neural representations of trained visual stimuli, a phenomenon known as visual perceptual learning (VPL). While attention to task-relevant stimuli plays an important role in such learning, Pavlovian stimulus-reinforcer associations are sufficient to drive VPL, even subconsciou...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11527-9

    authors： Arsenault JT,Vanduffel W

    更新日期：2019-08-09 00:00:00

  • Controlling spin current polarization through non-collinear antiferromagnetism.

    abstract：:The interconversion of charge and spin currents via spin-Hall effect is essential for spintronics. Energy-efficient and deterministic switching of magnetization can be achieved when spin polarizations of these spin currents are collinear with the magnetization. However, symmetry conditions generally restrict spin pola...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17999-4

    authors： Nan T,Quintela CX,Irwin J,Gurung G,Shao DF,Gibbons J,Campbell N,Song K,Choi S-,Guo L,Johnson RD,Manuel P,Chopdekar RV,Hallsteinsen I,Tybell T,Ryan PJ,Kim J-,Choi Y,Radaelli PG,Ralph DC,Tsymbal EY,Rzchowski MS,

    更新日期：2020-09-16 00:00:00

  • Causality matters in medical imaging.

    abstract：:Causal reasoning can shed new light on the major challenges in machine learning for medical imaging: scarcity of high-quality annotated data and mismatch between the development dataset and the target environment. A causal perspective on these issues allows decisions about data collection, annotation, preprocessing, a...

    journal_title：Nature communications

    pub_type： 杂志文章,评审

    doi：10.1038/s41467-020-17478-w

    authors： Castro DC,Walker I,Glocker B

    更新日期：2020-07-22 00:00:00

  • The acetyllysine reader BRD3R promotes human nuclear reprogramming and regulates mitosis.

    abstract：:It is well known that both recipient cells and donor nuclei demonstrate a mitotic advantage as observed in the traditional reprogramming with somatic cell nuclear transfer (SCNT). However, it is not known whether a specific mitotic factor plays a critical role in reprogramming. Here we identify an isoform of human bro...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10869

    authors： Shao Z,Zhang R,Khodadadi-Jamayran A,Chen B,Crowley MR,Festok MA,Crossman DK,Townes TM,Hu K

    更新日期：2016-03-07 00:00:00

  • Long-term isolation of European steppe outposts boosts the biome's conservation value.

    abstract：:The European steppes and their biota have been hypothesized to be either young remnants of the Pleistocene steppe belt or, alternatively, to represent relicts of long-term persisting populations; both scenarios directly bear on nature conservation priorities. Here, we evaluate the conservation value of threatened disj...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15620-2

    authors： Kirschner P,Záveská E,Gamisch A,Hilpold A,Trucchi E,Paun O,Sanmartín I,Schlick-Steiner BC,Frajman B,Arthofer W,STEPPE Consortium.,Steiner FM,Schönswetter P

    更新日期：2020-04-23 00:00:00

  • Spatially-resolved fluorescence-detected two-dimensional electronic spectroscopy probes varying excitonic structure in photosynthetic bacteria.

    abstract：:Conventional implementations of two-dimensional electronic spectroscopy typically spatially average over ~1010 chromophores spread over ~104 micron square area, limiting their ability to characterize spatially heterogeneous samples. Here we present a variation of two-dimensional electronic spectroscopy that is capable...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06619-x

    authors： Tiwari V,Matutes YA,Gardiner AT,Jansen TLC,Cogdell RJ,Ogilvie JP

    更新日期：2018-10-11 00:00:00

  • RC3H1 post-transcriptionally regulates A20 mRNA and modulates the activity of the IKK/NF-κB pathway.

    abstract：:The RNA-binding protein RC3H1 (also known as ROQUIN) promotes TNFα mRNA decay via a 3'UTR constitutive decay element (CDE). Here we applied PAR-CLIP to human RC3H1 to identify ∼ 3,800 mRNA targets with >16,000 binding sites. A large number of sites are distinct from the consensus CDE and revealed a structure-sequence ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8367

    authors： Murakawa Y,Hinz M,Mothes J,Schuetz A,Uhl M,Wyler E,Yasuda T,Mastrobuoni G,Friedel CC,Dölken L,Kempa S,Schmidt-Supprian M,Blüthgen N,Backofen R,Heinemann U,Wolf J,Scheidereit C,Landthaler M

    更新日期：2015-07-14 00:00:00

  • An autonomous DNA nanomachine maps spatiotemporal pH changes in a multicellular living organism.

    abstract：:Structural DNA nanotechnology seeks to build synthetic molecular machinery from DNA. DNA nanomachines are artificially designed assemblies that switch between defined conformations in response to an external cue. Though it has proved possible to create DNA machines and rudimentary walkers, the function of such autonom...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1340

    authors： Surana S,Bhat JM,Koushika SP,Krishnan Y

    更新日期：2011-06-07 00:00:00