Development and application of a method for Cr(III) determination in dairy products by HPLC-ICP-MS.

Abstract:

:This study describes the development of an analytical approach for the determination of Cr(III) in dairy products by microwave assisted extraction, complexation in situ by ethylenediaminetetraacetate (EDTA) and high performance liquid chromatography hyphenated to inductively coupled plasma-mass spectrometry (HPLC-ICP-MS). The extraction step was optimised by using an experimental design. A limit of quantification of 38µgkg-1dry weight (d.w.) was obtained whereas the bias (%) measured ranged from 10 to 18%. The repeatability and intermediate precision varied between 1.2-5.0% and 7.5-13.5%, respectively. The method was applied to the analysis of several dairy samples beforehand characterized in terms of Cr(VI) and total chromium (Crtotal). Cr(III) concentrations ranged from <13 to 255µgkg-1d.w. The results showed a good agreement between Cr(III) and Crtotal concentration levels.

journal_name

Food Chem

journal_title

Food chemistry

authors

Hernandez F,Jitaru P,Cormant F,Noël L,Guérin T

doi

10.1016/j.foodchem.2017.07.110

subject

Has Abstract

pub_date

2018-02-01 00:00:00

pages

183-188

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(17)31263-3

journal_volume

240

pub_type

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