Recyclable Polydimethylsiloxane Network Crosslinked by Dynamic Transesterification Reaction.

Abstract:

:This article reports preparation of a crosslinked polydimethylsiloxane (PDMS) network via dynamic transesterification reaction between PDMS-diglycidyl ether and pripol 1017 with Zn(OAc)2 as the catalyst. The thermal dynamic nature of the network was investigated by the creep-recovery and stress-relaxation tests. The synthesized PDMS elastomer showed excellent solvent resistance even under high temperature, and could be reprocessed by hot pressing at 180 °C with the mechanical properties maintained after 10 cycles. Application of the PDMS elastomer in constructing micro-patterned stamps repeatedly has been demonstrated. The high plastic temperature and good solvent resistance distinguish the research from other reported thermoplastic PDMS elastomers and broaden the practical application areas.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Zhang H,Cai C,Liu W,Li D,Zhang J,Zhao N,Xu J

doi

10.1038/s41598-017-11485-6

subject

Has Abstract

pub_date

2017-09-19 00:00:00

pages

11833

issue

1

issn

2045-2322

pii

10.1038/s41598-017-11485-6

journal_volume

7

pub_type

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