Plasmon-Enhanced Photocurrent using Gold Nanoparticles on a Three-Dimensional TiO2 Nanowire-Web Electrode.

Abstract:

:In this study, an anatase/rutile mixed-phase titanium dioxide (TiO2) hierarchical network deposited with Au nanoparticles (Au/TiO2 ARHN) was synthesized using a facile hydrothermal method followed by a simple calcination step. Such a unique structure was designed for improving the light harvest, charge transportation/separation, and the performance of photo-electro-chemical (PEC) cells. The properties of the as-synthesized Au/TiO2 ARHN in PEC cells were investigated by electrochemical measurements using a three-electrode system in a 1 M NaOH electrolyte. Remarkably, a 4.5-folds enhancement of the photocurrent for Au/TiO2 ARHN was observed as compared to that for TiO2 nanowire (NW), under AM1.5G solar illumination, suggesting its potential application in PEC cells. A mechanism has been proposed to explain the high photocurrent of Au/TiO2 ARHN in PEC water splitting.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Yen YC,Chen JA,Ou S,Chen YS,Lin KJ

doi

10.1038/srep42524

subject

Has Abstract

pub_date

2017-02-10 00:00:00

pages

42524

issn

2045-2322

pii

srep42524

journal_volume

7

pub_type

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