Equilibrium adsorption of caffeic, chlorogenic and rosmarinic acids on cationic cross-linked starch with quaternary ammonium groups.

Abstract:

:In the present study, the equilibrium adsorption of caffeic acid (CA) and its derivatives, namely, chlorogenic (CGA) and rosmarinic (RA) acids on cationic cross-linked starch (CCS) with degree of substitution of quaternary ammonium groups of 0.42 have been investigated in relation to the structure and acidity of phenolic acids. The Langmuir, Freundlich and Dubinin-Radushkevich adsorption models have been used to describe the equilibrium adsorption of CA, CGA and RA from their initial solutions and solutions having the equimolar amount of NaOH at different temperatures. In the case of adsorption from the initial solutions of acids the values of adsorption parameters were closely related to the dissociation constants of investigated acids. According to the increasing effectiveness of adsorption, phenolic acids could be arranged in the following order: CA

journal_name

Int J Biol Macromol

authors

Simanaviciute D,Klimaviciute R,Rutkaite R

doi

10.1016/j.ijbiomac.2016.12.006

subject

Has Abstract

pub_date

2017-02-01 00:00:00

pages

788-795

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(16)31810-4

journal_volume

95

pub_type

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