Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation.

Abstract:

:Thermal conductivity of two-dimensional (2D) materials is of interest for energy storage, nanoelectronics and optoelectronics. Here, we report that the thermal conductivity of molybdenum disulfide can be modified by electrochemical intercalation. We observe distinct behaviour for thin films with vertically aligned basal planes and natural bulk crystals with basal planes aligned parallel to the surface. The thermal conductivity is measured as a function of the degree of lithiation, using time-domain thermoreflectance. The change of thermal conductivity correlates with the lithiation-induced structural and compositional disorder. We further show that the ratio of the in-plane to through-plane thermal conductivity of bulk crystal is enhanced by the disorder. These results suggest that stacking disorder and mixture of phases is an effective mechanism to modify the anisotropic thermal conductivity of 2D materials.

journal_name

Nat Commun

journal_title

Nature communications

authors

Zhu G,Liu J,Zheng Q,Zhang R,Li D,Banerjee D,Cahill DG

doi

10.1038/ncomms13211

subject

Has Abstract

pub_date

2016-10-21 00:00:00

pages

13211

issn

2041-1723

pii

ncomms13211

journal_volume

7

pub_type

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