Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations.

Abstract:

:Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with . These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive π-stacking radical cation with single phenyl ring and reveals their conductivity has relationship with the stack structure which affected by the substituent.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Chen X,Gao F,Yang W

doi

10.1038/srep29314

subject

Has Abstract

pub_date

2016-07-11 00:00:00

pages

29314

issn

2045-2322

pii

srep29314

journal_volume

6

pub_type

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