Conductivity-limiting bipolar thermal conductivity in semiconductors.

Abstract:

:Intriguing experimental results raised the question about the fundamental mechanisms governing the electron-hole coupling induced bipolar thermal conduction in semiconductors. Our combined theoretical analysis and experimental measurements show that in semiconductors bipolar thermal transport is in general a "conductivity-limiting" phenomenon, and it is thus controlled by the carrier mobility ratio and by the minority carrier partial electrical conductivity for the intrinsic and extrinsic cases, respectively. Our numerical method quantifies the role of electronic band structure and carrier scattering mechanisms. We have successfully demonstrated bipolar thermal conductivity reduction in doped semiconductors via electronic band structure modulation and/or preferential minority carrier scatterings. We expect this study to be beneficial to the current interests in optimizing thermoelectric properties of narrow gap semiconductors.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Wang S,Yang J,Toll T,Yang J,Zhang W,Tang X

doi

10.1038/srep10136

subject

Has Abstract

pub_date

2015-05-13 00:00:00

pages

10136

issn

2045-2322

pii

srep10136

journal_volume

5

pub_type

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