A rapid space-resolved solid-phase microextraction method as a powerful tool to determine contaminants in wine based on their volatility.

Abstract:

:A novel space-resolved solid phase microextraction (SR-SPME) technique was developed to facilitate simultaneously analyte monitoring within heterogeneous samples. Graphene (G) and graphene oxide (GO) were coated separately to the segmented fibers which were successfully used for the solid-phase microextraction of two contaminants with dramatically different volatility: 2,4,6-trichloroanisole (TCA) and dibutyl phthalate (DBP). The space-resolved fiber showed good precision (5.4%, 6.8%), low detection limits (0.3ng/L, 0.3ng/L), and wide linearity (1.0-250.0ng/L, 1.0-250.0ng/L) under the optimized conditions for TCA and DBP, respectively. The method was applied to simultaneous analysis of the two contaminates with satisfactory recoveries, which were 96.96% and 98.20% for wine samples.

journal_name

Food Chem

journal_title

Food chemistry

authors

Liu M,Peng QQ,Chen YF,Tang Q,Feng Q

doi

10.1016/j.foodchem.2014.12.037

subject

Has Abstract

pub_date

2015-06-01 00:00:00

pages

12-6

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(14)01948-7

journal_volume

176

pub_type

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