Fluorination of metal phthalocyanines: single-crystal growth, efficient N-channel organic field-effect transistors, and structure-property relationships.

Abstract:

:The fluorination of p-type metal phthalocyanines produces n-type semiconductors, allowing the design of organic electronic circuits that contain inexpensive heterojunctions made from chemically and thermally stable p- and n-type organic semiconductors. For the evaluation of close to intrinsic transport properties, high-quality centimeter-sized single crystals of F16CuPc, F16CoPc and F16ZnPc have been grown. New crystal structures of F16CuPc, F16CoPc and F16ZnPc have been determined. Organic single-crystal field-effect transistors have been fabricated to study the effects of the central metal atom on their charge transport properties. The F16ZnPc has the highest electron mobility (~1.1 cm(2) V(-1) s(-1)). Theoretical calculations indicate that the crystal structure and electronic structure of the central metal atom determine the transport properties of fluorinated metal phthalocyanines.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Jiang H,Ye J,Hu P,Wei F,Du K,Wang N,Ba T,Feng S,Kloc C

doi

10.1038/srep07573

subject

Has Abstract

pub_date

2014-12-19 00:00:00

pages

7573

issn

2045-2322

pii

srep07573

journal_volume

4

pub_type

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