A new strategy for integrating abundant oxygen functional groups into carbon felt electrode for vanadium redox flow batteries.

Abstract:

:The effects of surface treatment combining corona discharge and hydrogen peroxide (H2O2) on the electrochemical performance of carbon felt electrodes for vanadium redox flow batteries (VRFBs) have been thoroughly investigated. A high concentration of oxygen functional groups has been successfully introduced onto the surface of the carbon felt electrodes by a specially designed surface treatment, which is mainly responsible for improving the energy efficiency of VRFBs. In addition, the wettability of the carbon felt electrodes also can be significantly improved. The energy efficiency of the VRFB cell employing the surface modified carbon felt electrodes is improved by 7% at high current density (148 mA cm(-2)). Such improvement is attributed to the faster charge transfer and better wettability allowed by surface-active oxygen functional groups. Moreover, this method is much more competitive than other surface treatments in terms of processing time, production costs, and electrochemical performance.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Kim KJ,Lee SW,Yim T,Kim JG,Choi JW,Kim JH,Park MS,Kim YJ

doi

10.1038/srep06906

subject

Has Abstract

pub_date

2014-11-04 00:00:00

pages

6906

issn

2045-2322

pii

srep06906

journal_volume

4

pub_type

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