Effects of degree of dissociation of acid used on hydrolytic durability of ceramic primer.

Abstract:

:In this study, effects of the degree of dissociation of acids on the hydrolysis rate of methoxy group in γ-methacryloxypropyltrimethoxysilane (γ-MPS) and the adsorption characteristics of γ-MPS on ceramic surfaces were studied using acetic, phosphoric, and hydrochloric acids. Hydrolytic stability of γ-MPS adsorption layer at the resin-ceramic interface was thus examined. (29)Si NMR observations of acidactivated γ-MPS and contact angle measurements following ceramic surface silanization were performed. Bond strengths of resin to the silanized ceramic surfaces were measured. Statistical analyses of shear bond strength and contact angle data were performed. Increase in the degree of dissociation of the acid used increased the hydrolysis rate of methoxy group in γ-MPS, but lowered the contact angle to the silanized ceramic surface. Decrease in the contact angle increased the hydrolytic stability of γ-MPS adsorption layer.

journal_name

Dent Mater J

journal_title

Dental materials journal

authors

Aoki N,Kimoto S,Tanimura H,Nishiyama N,Aida M

doi

10.4012/dmj.2013-319

subject

Has Abstract

pub_date

2014-01-01 00:00:00

pages

614-20

issue

5

eissn

0287-4547

issn

1881-1361

pii

DN/JST.JSTAGE/dmj/2013-319

journal_volume

33

pub_type

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