Framework-flexibility driven selective sorption of p-xylene over other isomers by a dynamic metal-organic framework.

Abstract:

:Chemical separation has great importance in industrial applications. Separation of xylene isomers still prevails to be one of the most important challenges in chemical industry, due to the large amount of commercial use of p-xylene in the production of beverage bottles, fibers and films. A novel Zn(II)-based dynamic coordination framework based on flexible ether-linkage, exhibiting selective adsorption of p-Xylene over its congener C8-alkyl aromatic isomers at ambient conditions is reported. Notably, no dynamic structure based MOF compound is known in the literature which shows clear preference of p-xylene over other isomers. This type of framework-breathing and guest-induced reversible solid-state structural transformations with unique adsorption selectivity can be exploited purposefully to develop smart functional host materials capable of industrially important chemical separations.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Mukherjee S,Joarder B,Manna B,Desai AV,Chaudhari AK,Ghosh SK

doi

10.1038/srep05761

subject

Has Abstract

pub_date

2014-07-21 00:00:00

pages

5761

issn

2045-2322

pii

srep05761

journal_volume

4

pub_type

杂志文章
  • Chemerin regulates β-cell function in mice.

    abstract::Although various function of chemerin have been suggested, its physiological role remains to be elucidated. Here we show that chemerin-deficient mice are glucose intolerant irrespective of exhibiting reduced macrophage accumulation in adipose tissue. The glucose intolerance was mainly due to increased hepatic glucose ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep00123

    authors: Takahashi M,Okimura Y,Iguchi G,Nishizawa H,Yamamoto M,Suda K,Kitazawa R,Fujimoto W,Takahashi K,Zolotaryov FN,Hong KS,Kiyonari H,Abe T,Kaji H,Kitazawa S,Kasuga M,Chihara K,Takahashi Y

    更新日期:2011-01-01 00:00:00

  • p53 dynamics upon response element recognition explored by molecular simulations.

    abstract::p53 is a representative transcription factor that activates multiple target genes. To realize stimulus-dependent specificities, p53 has to recognize targets with structural variety, of which molecular mechanisms are largely unknown. Here, we conducted a series of long-time scale (totally more than 100-ms) coarse-grain...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep17107

    authors: Terakawa T,Takada S

    更新日期:2015-11-24 00:00:00

  • Vertical migration by bulk phytoplankton sustains biodiversity and nutrient input to the surface ocean.

    abstract::Phytoplankton subsumes the great variety of unicellular photoautotrophs that perform roughly half of Earth's primary production. They achieve this despite their challenging oceanic habitat, with opposing vertical gradients of nutrients (which often limit their growth near the surface) and light (which becomes limiting...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-57890-2

    authors: Wirtz K,Smith SL

    更新日期:2020-01-24 00:00:00

  • The adaptive value of camouflage and colour change in a polymorphic prawn.

    abstract::Camouflage has been a textbook example of natural selection and adaptation since the time of the earliest evolutionists. However, aside from correlational evidence and studies using artificial dummy prey, experiments directly showing that better camouflaged prey to predator vision are at reduced risk of attack are lac...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-34470-z

    authors: Duarte RC,Stevens M,Flores AAV

    更新日期:2018-10-30 00:00:00

  • Disease control efficacy of 32,33-didehydroroflamycoin produced by Streptomyces rectiviolaceus strain DY46 against gray mold of tomato fruit.

    abstract::Despite the efficacy of synthetic fungicides in controlling postharvest diseases, public concerns regarding chemical residues in food and an increase in drug-resistant strains of pathogens have led to a need for new agents to control postharvest diseases. The current study was performed to find control agents of micro...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-49779-6

    authors: Kim JD,Park MY,Jeon BJ,Kim BS

    更新日期:2019-09-19 00:00:00

  • The protective value of a defensive display varies with the experience of wild predators.

    abstract::Predation has driven the evolution of diverse adaptations for defence among prey, and one striking example is the deimatic display. While such displays can resemble, or indeed co-occur with, aposematic 'warning' signals, theory suggests deimatic displays may function independently of predator learning. The survival va...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-36995-9

    authors: Umbers KDL,White TE,De Bona S,Haff T,Ryeland J,Drinkwater E,Mappes J

    更新日期:2019-01-24 00:00:00

  • Improved therapeutic potential of tapentadol employing cationic exchange resins as carriers in neuropathic pain: evidence from pharmacokinetic and pharmacodynamics study.

    abstract::Current investigation was endeavoured to overcome problem of poor palatability and bioavailability of centrally acting analgesic, tapentadol (TAP) by formulating controlled release drug-resin complexes (DRCs). The technology encompassed in preparation of DRCs involved chemisorption of TAP to weak cationic resins (Kyro...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-21214-2

    authors: Sharma M,Soni R

    更新日期:2018-02-12 00:00:00

  • Generalized Haldane models on laser-coupling optical lattices.

    abstract::We propose two generalized Haldane models on laser-coupling optical lattices. Laser-assisted nearest neighbour tunnelings generate artificial staggered magnetic flux, facilitating the realization of topological nontrivial band structures. As generalizations of Haldane model, these models support topological insulator ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-30503-9

    authors: Liu W,Lin Z,Wang ZD,Chen Y

    更新日期:2018-08-27 00:00:00

  • Suppression of chorismate synthase, which is localized in chloroplasts and peroxisomes, results in abnormal flower development and anthocyanin reduction in petunia.

    abstract::In plants, the shikimate pathway generally occurs in plastids and leads to the biosynthesis of aromatic amino acids. Chorismate synthase (CS) catalyses the last step of the conversion of 5-enolpyruvylshikimate 3-phosphate (EPSP) to chorismate, but the role of CS in the metabolism of higher plants has not been reported...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-67671-6

    authors: Zhong S,Chen Z,Han J,Zhao H,Liu J,Yu Y

    更新日期:2020-07-02 00:00:00

  • Standoff Detection of Uranium and its Isotopes by Femtosecond Filament Laser Ablation Molecular Isotopic Spectrometry.

    abstract::The ability to perform not only elementally but also isotopically sensitive detection and analysis at standoff distances is impor-tant for remote sensing applications in diverse ares, such as nuclear nonproliferation, environmental monitoring, geophysics, and planetary science. We demonstrate isotopically sensitive re...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep43852

    authors: Hartig KC,Ghebregziabher I,Jovanovic I

    更新日期:2017-03-08 00:00:00

  • Regulation of the Human Phosphatase PTPN4 by the inter-domain linker connecting the PDZ and the phosphatase domains.

    abstract::Human protein tyrosine phosphatase non-receptor type 4 (PTPN4) has been shown to prevent cell death. The active form of human PTPN4 consists of two globular domains, a PDZ (PSD-95/Dlg/ZO-1) domain and a phosphatase domain, tethered by a flexible linker. Targeting its PDZ domain abrogates this protection and triggers a...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-08193-6

    authors: Caillet-Saguy C,Toto A,Guerois R,Maisonneuve P,di Silvio E,Sawyer K,Gianni S,Wolff N

    更新日期:2017-08-11 00:00:00

  • Transition in the equilibrium distribution function of relativistic particles.

    abstract::We analyze a transition from single peaked to bimodal velocity distribution in a relativistic fluid under increasing temperature, in contrast with a non-relativistic gas, where only a monotonic broadening of the bell-shaped distribution is observed. Such transition results from the interplay between the raise in therm...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep00611

    authors: Mendoza M,Araújo NA,Succi S,Herrmann HJ

    更新日期:2012-01-01 00:00:00

  • Phonatory and articulatory representations of speech production in cortical and subcortical fMRI responses.

    abstract::Speaking involves coordination of multiple neuromotor systems, including respiration, phonation and articulation. Developing non-invasive imaging methods to study how the brain controls these systems is critical for understanding the neurobiology of speech production. Recent models and animal research suggest that reg...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-61435-y

    authors: Correia JM,Caballero-Gaudes C,Guediche S,Carreiras M

    更新日期:2020-03-11 00:00:00

  • Electron cyclotron motion excited surface plasmon and radiation with orbital angular momentum on a semiconductor thin film.

    abstract::In this work, surface plasmons (SPs) on a germanium (Ge) thin film in terahertz (THz) region that are excited by electron cyclotron motion (ECM) and the subsequent SP emission (SPE) by adding Ge gratings on the film are explored by finite-difference time-domain (FDTD) and particle-in-cell FDTD (PIC-FDTD) simulations. ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-73725-6

    authors: Lan YC,Shen CH,Chen CM

    更新日期:2020-10-07 00:00:00

  • Evidence for the importance of post-transcriptional regulatory changes in ovarian cancer progression and the contribution of miRNAs.

    abstract::High-throughput technologies have identified significant changes in patterns of mRNA expression over cancer development but the functional significance of these changes often rests upon the assumption that observed changes in levels of mRNA accurately reflect changes in levels of their encoded proteins. We systematica...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-08502-z

    authors: Zhang M,Matyunina LV,Walker LD,Chen W,Xiao H,Benigno BB,Wu R,McDonald JF

    更新日期:2017-08-15 00:00:00

  • Nitrogen uptake kinetics and saltmarsh plant responses to global change.

    abstract::Coastal wetlands are important carbon sinks globally, but their ability to store carbon hinges on their nitrogen (N) supply and N uptake dynamics of dominant plant species. In terrestrial ecosystems, uptake of nitrate (NO3-) and ammonium (NH4+) through roots can strongly influence N acquisition rates and their respons...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-23349-8

    authors: Cott GM,Caplan JS,Mozdzer TJ

    更新日期:2018-03-29 00:00:00

  • Plasmon-Enhanced Photocurrent using Gold Nanoparticles on a Three-Dimensional TiO2 Nanowire-Web Electrode.

    abstract::In this study, an anatase/rutile mixed-phase titanium dioxide (TiO2) hierarchical network deposited with Au nanoparticles (Au/TiO2 ARHN) was synthesized using a facile hydrothermal method followed by a simple calcination step. Such a unique structure was designed for improving the light harvest, charge transportation/...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep42524

    authors: Yen YC,Chen JA,Ou S,Chen YS,Lin KJ

    更新日期:2017-02-10 00:00:00

  • Evidence and mapping of extinction debts for global forest-dwelling reptiles, amphibians and mammals.

    abstract::Evidence of extinction debts for the global distributions of forest-dwelling reptiles, mammals and amphibians was tested and the debt magnitude was estimated and mapped. By using different correlation tests and variable importance analysis, the results showed that spatial richness patterns for the three forest-dwellin...

    journal_title:Scientific reports

    pub_type: 历史文章,杂志文章

    doi:10.1038/srep44305

    authors: Chen Y,Peng S

    更新日期:2017-03-16 00:00:00

  • Increase in predation risk and trophic level induced by nocturnal visits of piscivorous fishes in a temperate seagrass bed.

    abstract::The majority of surveys on food webs of aquatic ecosystems have been conducted during the day owning to difficulties in sampling animals at night. In this study, to examine diurnal changes in predator-prey interactions in a temperate seagrass Zostera marina bed, a quantitative day/night survey of fish, the dominant an...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-04217-3

    authors: Shoji J,Mitamura H,Ichikawa K,Kinoshita H,Arai N

    更新日期:2017-06-20 00:00:00

  • A comparison of trunk circumference and width indices for hypertension and type 2 diabetes in a large-scale screening: a retrospective cross-sectional study.

    abstract::Anthropometric indices determine important risk factors for many chronic diseases. However, to date, no study has simultaneously analyzed the capabilities of trunk circumference and width indices to identify hypertension and type 2 diabetes in a large-scale screening study. The objectives of this study were to examine...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-31624-x

    authors: Lee BJ,Ku B

    更新日期:2018-09-05 00:00:00

  • Identification of a CD133-CD55- population functions as a fetal common skeletal progenitor.

    abstract::In this study, we identified a CD105+CD90.1-CD133-CD55- (CD133-CD55-) population in the fetal skeletal element that can generate bone and bone marrow. Besides osteoblasts and chondrocytes, the CD133-CD55- common progenitors can give rise to marrow reticular stromal cells and perivascular mesenchymal progenitors sugges...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep38632

    authors: Weng L,Hu X,Kumar B,Garcia M,Todorov I,Jung X,Marcucci G,Forman SJ,Chen CC

    更新日期:2016-12-08 00:00:00

  • A novel approach for discovering stochastic models behind data applied to El Niño-Southern Oscillation.

    abstract::Stochastic differential equations (SDEs) are ubiquitous across disciplines, and uncovering SDEs driving observed time series data is a key scientific challenge. Most previous work on this topic has relied on restrictive assumptions, undermining the generality of these approaches. We present a novel technique to uncove...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-021-81162-2

    authors: Olson R,An SI,Kim SK,Fan Y

    更新日期:2021-01-29 00:00:00

  • Artificial photosynthesis of oxalate and oxalate-based polymer by a photovoltaic reactor.

    abstract::A photovoltaic reactor was designed for artificial photosynthesis, based on the reactions involved in high energy hydrogen atoms, which were produced from water electrolysis. Water and CO2, under the conditions studied, were converted to oxalate (H2C2O4) and a polymer. This was the first time that the oxalates and oxa...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep03572

    authors: Nong G,Chen S,Xu Y,Huang L,Zou Q,Li S,Mo H,Zhu P,Cen W,Wang S

    更新日期:2014-01-06 00:00:00

  • The effects of playing music on mental health outcomes.

    abstract::The association between active musical engagement (as leisure activity or professionally) and mental health is still unclear, with earlier studies reporting contrasting findings. Here we tested whether musical engagement predicts (1) a diagnosis of depression, anxiety, schizophrenia, bipolar or stress-related disorder...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-49099-9

    authors: Wesseldijk LW,Ullén F,Mosing MA

    更新日期:2019-08-30 00:00:00

  • Acoustic indices provide information on the status of coral reefs: an example from Moorea Island in the South Pacific.

    abstract::Different marine habitats are characterised by different soundscapes. How or which differences may be representative of the habitat characteristics and/or community structure remains however to be explored. A growing project in passive acoustics is to find a way to use soundscapes to have information on the habitat an...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep33326

    authors: Bertucci F,Parmentier E,Lecellier G,Hawkins AD,Lecchini D

    更新日期:2016-09-15 00:00:00

  • A twenty-year deposition record of elemental carbon in Northern Japan retrieved from archived filters.

    abstract::The black carbon or elemental carbon (EC) content in ice and snow has been a concern in climate change studies, but time-series records have mostly been obtained from glacier ice-core samples in limited geographical locations, such as the Arctic or high mountains. This is the first study to present decade-long records...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-61067-2

    authors: Kaneyasu N,Matsumoto K,Yamaguchi T,Noguchi I,Murao N,Yasunari TJ,Ikemori F

    更新日期:2020-03-18 00:00:00

  • Uncaria tomentosa improves insulin sensitivity and inflammation in experimental NAFLD.

    abstract::We investigated the effect of the crude herbal extract from Uncaria tomentosa (UT) on non-alcoholic fatty liver disease (NAFLD) in two models of obesity: high fat diet (HFD) and genetically obese (ob/ob) mice. Both obese mouse models were insulin resistant and exhibited an abundance of lipid droplets in the hepatocyte...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-29044-y

    authors: Araujo LCC,Feitosa KB,Murata GM,Furigo IC,Teixeira SA,Lucena CF,Ribeiro LM,Muscará MN,Costa SKP,Donato J Jr,Bordin S,Curi R,Carvalho CRO

    更新日期:2018-07-20 00:00:00

  • Simulated effect of calcification feedback on atmospheric CO2 and ocean acidification.

    abstract::Ocean uptake of anthropogenic CO2 reduces pH and saturation state of calcium carbonate materials of seawater, which could reduce the calcification rate of some marine organisms, triggering a negative feedback on the growth of atmospheric CO2. We quantify the effect of this CO2-calcification feedback by conducting a se...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep20284

    authors: Zhang H,Cao L

    更新日期:2016-02-03 00:00:00

  • Individual versus team heart rate variability responsiveness analyses in a national soccer team during training camps.

    abstract::Heart rate variability (HRV) analyses can be performed using group or individual changes. Individual changes could be of potential interest during training camps for national soccer teams. The purpose of this study was to compare whether analysis of individual daily HRV could detect changes in cardiac autonomic respon...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-68698-5

    authors: Muñoz-López A,Naranjo-Orellana J

    更新日期:2020-07-16 00:00:00

  • Highly efficient organic tandem solar cell with a SubPc interlayer based on TAPC:C70 bulk heterojunction.

    abstract::We report a small molecule tandem organic photovoltaic (OPV) cell with a high power conversion efficiency (PCE) of 7.27%. This cell contains two subcells with an identical mixed active layer of C70:5 wt%TAPC (1,1-bis-(4-bis(4-methyl-phenyl)-amino-phenyl)-cyclohexane). The performance was dramatically improved by simpl...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep23916

    authors: Gao Y,Jin F,Li W,Su Z,Chu B,Wang J,Zhao H,Wu H,Liu C,Hou F,Lin T,Song Q

    更新日期:2016-04-01 00:00:00