Electrochemically tunable thermal conductivity of lithium cobalt oxide.

Abstract:

:Using time-domain thermoreflectance, the thermal conductivity and elastic properties of a sputter deposited LiCoO2 film, a common lithium-ion cathode material, are measured as a function of the degree of lithiation. Here we report that via in situ measurements during cycling, the thermal conductivity of a LiCoO2 cathode reversibly decreases from ~5.4 to 3.7 W m(-1) K(-1), and its elastic modulus decreases from 325 to 225 GPa, as it is delithiated from Li1.0CoO2 to Li0.6CoO2. The dependence of the thermal conductivity on lithiation appears correlated with the lithiation-dependent phase behaviour. The oxidation-state-dependent thermal conductivity of electrolytically active transition metal oxides provides opportunities for dynamic control of thermal conductivity and is important to understand for thermal management in electrochemical energy storage devices.

journal_name

Nat Commun

journal_title

Nature communications

authors

Cho J,Losego MD,Zhang HG,Kim H,Zuo J,Petrov I,Cahill DG,Braun PV

doi

10.1038/ncomms5035

subject

Has Abstract

pub_date

2014-06-03 00:00:00

pages

4035

issn

2041-1723

pii

ncomms5035

journal_volume

5

pub_type

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