Photoresponsive supramolecular complexes as efficient DNA regulator.

Abstract:

:Two supramolecular complexes of trans-1⊂CB[8] and trans-2⊂CB[8] were successfully achieved by the controlled selective complexation process of cucurbit[8]uril (CB[8]) with hetero-guest pair containing azobenzene and bispyridinium moieties in aqueous solution, exhibiting the reversibly light-driven movements of CB[8] upon the photocontrollable isomerization of azophenyl axle components. Significantly, the obtained bistable supramolecular complexes and their corresponding [2]pseudorotaxanes could act as a promising concentrator and cleavage agent to regulate the binding behaviors with DNA molecules.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Cheng HB,Zhang YM,Xu C,Liu Y

doi

10.1038/srep04210

subject

Has Abstract

pub_date

2014-02-27 00:00:00

pages

4210

issn

2045-2322

pii

srep04210

journal_volume

4

pub_type

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