Abstract：
:Understanding the chemical and physical properties of metal/graphene oxide (M/GO) interfaces is important when GO is used in electronic and electrochemical devices because the metal layer must be firmly attached to GO. Here, permeation of metal from the surface into GO paper bulk at the M/GO interface was observed at room temperature for metals such as Cu, Ag, Ni, Au, and Pt. Cu, Ag, and Ni quickly permeated GO as ions into the bulk under humid conditions. At first, these metals changed to hydrated ions as a result of redox reactions (with reduction of GO) at the surface, and then permeated the interlayers. Au and Pt were observed to permeate GO as atoms into the GO bulk at room temperature, although the permeation rates were low. These surprising results are considered to be due to the presence of many defects and/or edges with oxygenated groups in the GO paper.
journal_name
Sci Repjournal_title
Scientific reportsauthors
Ogata C,Koinuma M,Hatakeyama K,Tateishi H,Asrori MZ,Taniguchi T,Funatsu A,Matsumoto Ydoi
10.1038/srep03647subject
Has Abstractpub_date
2014-01-13 00:00:00pages
3647issn
2045-2322pii
srep03647journal_volume
4pub_type
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