Synthesis of stereoisomers of 8-methyl-2-decanol and esters attractive to severalDiabrotica sp.

Abstract:

:Details of the syntheses of the four stereoisomers of 8-methyl-2-decanol and its propanoate ester are given. The racemic ester, two of its stereoisomers, and one stereoisomer as an acetate are attractive to several species ofDiabrotica. The key steps in the syntheses involve high-performance liquid chromatograpic resolutions of diastereomers to achieve high configurational enrichment of each site and generation of (R)-2-methylbutyric acid by chemical degradation ofD-isoleucine.

journal_name

J Chem Ecol

authors

Sonnet PE,Carney RL,Henrick C

doi

10.1007/BF01012138

subject

Has Abstract

pub_date

1985-10-01 00:00:00

pages

1371-87

issue

10

eissn

0098-0331

issn

1573-1561

journal_volume

11

pub_type

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