Abstract:
:Details of the syntheses of the four stereoisomers of 8-methyl-2-decanol and its propanoate ester are given. The racemic ester, two of its stereoisomers, and one stereoisomer as an acetate are attractive to several species ofDiabrotica. The key steps in the syntheses involve high-performance liquid chromatograpic resolutions of diastereomers to achieve high configurational enrichment of each site and generation of (R)-2-methylbutyric acid by chemical degradation ofD-isoleucine.
journal_name
J Chem Ecoljournal_title
Journal of chemical ecologyauthors
Sonnet PE,Carney RL,Henrick Cdoi
10.1007/BF01012138subject
Has Abstractpub_date
1985-10-01 00:00:00pages
1371-87issue
10eissn
0098-0331issn
1573-1561journal_volume
11pub_type
杂志文章abstract::Various applications of a novel sampling procedure in chemical ecology are outlined. The stir bar extraction method features the analytical reproducibility needed in recording the analytical profiles of volatile and semivolatile components of biological mixtures. This methodology has been demonstrated here through the...
journal_title:Journal of chemical ecology
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abstract::Pheromone communication systems have a reliable signal with a restricted window of amounts and ratios released and perceived. We propose a model based on a Gaussian response profile that allows a quantification of the response peak (location of optimum) and a measure of the peak width (response window). Interpreting t...
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