Control self-assembly of hydrazide-based cyclic hexamers: in or out.

Abstract:

:By moving the alkoxy group on the spacer from position 5 to position 4 to add another protocol for the algorithm for intermolecular and intramolecular hydrogen bonding interactions, highly regioselectivity of noncovalent synthesis of the hydrazide-based cyclic hexamers was achieved: one out of thirteen possible isomeric cyclic hexamers selectively formed and thus precise control of the two hydrazide units in the cyclic hexamers (in or out) was accomplished.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Yang Y,Huang F,Chen CF,Xia M,Cai Q,Qian FJ,Xiang J

doi

10.1038/srep01059

subject

Has Abstract

pub_date

2013-01-01 00:00:00

pages

1059

issn

2045-2322

journal_volume

3

pub_type

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